The Complexation of Calix[6]Arene Sulfoxide Derivative with Uranium

Yin An Pi; Jing Song Wang; Qing Wei Guo; Hui Yan Mo; Yong Feng Xia; Xiao Liang Zou

doi:10.4028/www.scientific.net/AMR.842.170

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 842The Complexation of Calix[6]Arene Sulfoxide...

The Complexation of Calix[6]Arene Sulfoxide Derivative with Uranium

Abstract:

Calix[6]arene carbon chain alkyl sulfoxide derivative have been successfully synthesized. IR spectra confirmed the introduction of sulfoxide group on calix[6]arene. UV spectra indicated that calix[6]arene sulfoxide derivative has a high complexation of uranium. The coordination ratio between the calix[6]arene sulfoxide derivative with uranium is 3:2, which was determined by Job’s method. Extraction experiments showed that the extraction efficiency of uranium is able to achieve 73.8%, which suggested the potential application of calix[6]arene sulfoxide derivative as an excellent uranium extraction agent.

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Periodical:

Advanced Materials Research (Volume 842)

Pages:

170-174

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.842.170

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Online since:

November 2013

Authors:

Yin An Pi, Jing Song Wang*, Qing Wei Guo, Hui Yan Mo, Yong Feng Xia, Xiao Liang Zou

Keywords:

Calix[6]Arene Sulfoxide Derivative, Complexation, Extraction, Uranium

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