Effect of Bis (Triethoxysilylpropyl) Tetrasulfide on Physical Properties of Rice Husk Fiber/Natural Rubber Composites

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In this study, rice husk fiber (RHF), a byproduct from rice milling process, was used as reinforcing filler for natural rubber (NR). Generally, RHF surface and NR have different polarity. Therefore, fiber surface treatment was employed in this work to improve compatibility between RHF and NR. RHF was pretreated with alkali solution for 2 h (2ALT) before treating with various bis (triethoxysilylpropyl) tetrasulfide (Si69) contents, i.e., 2, 5 and 10 wt%. Physical properties of RHF and RHF/NR composites were characterized. FTIR spectra of Si69 treated RHF (ST) confirmed the appearance of Si69 on RHF surface. With increasing Si69 content, the peak position of FTIR absorption bands of ST did not changed. For NR composites, scorch time of ST/NR composites was longer than that of 2ALT/NR composites. With increasing Si69 content, there was no changed in scorch time of NR composites. ST/NR composites showed the maximum values of M100, M300, tensile strength and tear strength at Si69 content of 5 wt% indicating the improvement of rubber-fiber interaction and fiber dispersion in NR matrix.

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263-266

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November 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] F. Martí-Ferrer, F. Vilaplana, A. Ribes-Greus, A. Benedito-Borrás, C. Sanz-Box, Flour rice husk as filler in block copolymer polypropylene: Effect of different coupling agents, J. Appl. Polym. Sci. 99 (2006) 1823-1831.

DOI: 10.1002/app.22717

Google Scholar

[2] R. Nordin, C.M.S. Said, H. Ismail, Properties of rice husk powder/natural rubber composites. Solid State Sci, Technol. 15 (2007) 83-91.

Google Scholar

[3] H.S. Kim, S. Kim, H.J. Kim, Enhanced interfacial adhesion of bioflour-filled poly(propylene) biocomposites by electron-beam irradiation, Macromol Mater Eng, 291 (2006) 762-772.

DOI: 10.1002/mame.200600121

Google Scholar

[4] H. Ismail, N. Othman, M. Komethi, Curing characteristics and mechanical properties of rattan-powder-filled natural rubber composites as a function of filler loading and silane coupling agent, J. Appl. Polym. Sci. 123 (2012) 2805-2811.

DOI: 10.1002/app.34730

Google Scholar

[5] S. Thongsang, N. Sombatsompop, Effect of NaOH and Si69 treatments on the properties of fly ash/natural rubber composites, Polym. Composit. 27 (2006) 30-40.

DOI: 10.1002/pc.20163

Google Scholar

[6] P. J. Flory, Principles of polymer chemistry, Cornell University Press, New York, (1953).

Google Scholar

[7] L. Luduena, D. Fasce, V.A. Alvarez, P.M. Stefani, Nanocellulose from rice husk following alkaline treatment to remove silica, BioRes. 6 (2011) 1440-1453.

DOI: 10.15376/biores.6.2.1440-1453

Google Scholar

[8] N. Lopattananon, D Jitkalong, M. Seadan, Hybridized reinforcement of natural rubber with silane-modified short cellulose fibers and silica, J. Appl. Polym. Sci. 120 (2011) 3242-3254.

DOI: 10.1002/app.33374

Google Scholar

[9] C. Thongpin, C. Sangnil, P. Suerkong, A. Pongpilaiprertti, N. Sombatsompop, The effect of excess silane-69 used for surface modification on cure characteristic and mechanical properties of precipitated silica filled natural rubber (PSi/NR), Adv. Mater. Res. 79-82 (2009).

DOI: 10.4028/www.scientific.net/amr.79-82.2171

Google Scholar

[10] P. Sae-oui, U. Thepsuwan, K. Hatthapanit, Effect of curing system on reinforcing efficiency of silane coupling agent, Polym. Test. 23 (2004) 397-403.

DOI: 10.1016/j.polymertesting.2003.10.002

Google Scholar