Formic Acid Production from Hydrothermal Reaction of Cellulose

Article Preview

Abstract:

The conversion of cellulose under the hydrothermal condition was studied in an autoclave reactor. The reaction factors, such as oxygen supply and alkaline concentration was clearly investigated. A highest formic acid yield of about 27% was obtained. And also, other organic acid production was greatly produced. Besides formic acid, glycolic acid, acetic acid and lactic acid were also produced in alkaline oxidation of cellulose, with a total organic acid of up to 50%. It shows great potential for organic acid production from hydrothermal oxidation of cellulose.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 860-863)

Pages:

485-489

Citation:

Online since:

December 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] E.L. Kunkes, D.A. Simonetti, R.M. West, J.C. Serrano-Ruiz, C.A. Gartner, J.A. Dumesic: Science 322(2008), p.417.

Google Scholar

[2] N. Akiya, P.E. Savage: Chem. Rev. 102 (2002), p.2725.

Google Scholar

[3] Z. Fang, T. Minowa, C. Fang, R.L. Smith: Int. J. Hydrogen Energy 33 (2008), p.981.

Google Scholar

[4] Z.M. Fan, L. Yuan, R. Chatterjee: Plot One, 4(2009), p.4432.

Google Scholar

[5] F.M. Jin, J. Yun, G.M. Li, A. Kishita, K. Tohji, H. Enomoto: Green Chemistry 10(2008), p.612.

Google Scholar

[6] F. Joó: ChemSusChem 1(2008), p.805.

Google Scholar

[7] S. Uhma, H.J. Lee, J. Lee: Phys. Chem. Chem. Phys. 11(2009), p.9326.

Google Scholar

[8] L. Calvo, D. Vallejo: Ind. Eng. Chem. Res. 41(2002), p.6503.

Google Scholar