Synthesis, Characterization and Electrochemistry of Cathode Material Li [Li0.2Mn0.54Ni0.13Co0.13]O2 Nanofibers Prepared by Electrospinning for Lithium Ion Batteries

Fei Yu; Bo Rong Wu; Hong Liang Xu; Feng Wu

doi:10.4028/www.scientific.net/AMR.860-863.928

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Synthesis, Characterization and Electrochemistry of Cathode Material Li [Li_0.2Mn_0.54Ni_0.13Co_0.13]O₂ Nanofibers Prepared by Electrospinning for Lithium Ion Batteries

Abstract:

Nanofibers of Li [Li_0.2Mn_0.54Ni_0.13Co_0.13]O₂ with high crystallinity were easily synthesized by electrospinning. Scanning electron microscopy (SEM) showed that precursor wires were glossy, and the diameters of oxide calcined at 800°C were 50-200 nm. And X-ray diffraction (XRD) exhibited perfect crystal structure. The electrochemical properties of materials with the specific morphology were significantly improved. The first charge/discharge capacity was around 309.3 and 270.2 mAh·g^-1at 25 mA·g^-1, and the first coulomb efficiency (87.4%) represented a good efficiency for Li₂MnO₃-type electrodes. After 20 cycles, discharge capacity was over 200 mAh·g^-1 at 25 mA·g^-1, and capacity retention was 79.8% at 250 mA·g^-1.Owing to its simplicity and applicability, the electrospinning method is an promising method to fabricate high performance Li [Li_0.2Mn_0.54Ni_0.13Co_0.13]O₂ materials for lithium ion batteries.

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Periodical:

Advanced Materials Research (Volumes 860-863)

Pages:

928-932

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.860-863.928

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Online since:

December 2013

Authors:

Fei Yu, Bo Rong Wu, Hong Liang Xu, Feng Wu

Keywords:

Cathode, Electro-Spinning, Li[Li_0.2Mn_0.54Ni_0.13Co_0.13]O₂, Nanostructure

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References

[1] Yanhuai Ding, Ping Zhang, Zhilin Long, Yong Jiang, Fu Xu: Journal of Alloys and Compounds. Vol. 487 (2009), pp.507-510.

Google Scholar

[2] Z. Lu, R.A. Donaberger L.Y. Beaulieu, C.L. Thomas, J.R. Dahn: Journal of Electrochemical Society. Vol. 149 (2002), p.778.

Google Scholar

[3] Y.J. Park, Y.S. Hong, X. Wu, K.S. Ryu, S.H. Chang: Journal of Power Sources. Vol. 129(2004), p.288.

Google Scholar

[4] D.A.R. Barkhouse, J.R. Dahn: Journal of Electrochemical Society. Vol. 152 (2005), p.746.

Google Scholar

[5] J. Jiang, K.W. Eberman, L.J. Krause: Journal of Electrochemical Society. Vol. 152 (2005), p.1879.

Google Scholar

[6] S.J. Shi, J.P. Tu,Y.Y. Tang: Journal of Power Sources. Vol. 241(2013), pp.186-195.

Google Scholar

[7] Min-Kyu Song, Soojin Park, Faisal M. Alamgir: Materials Science and Engineering. Vol. 72 (2011), pp.203-252.

Google Scholar

[8] Y. Gu, D. Chen, X. Jiao: J. Phys. Chem. Vol. 109 (2005), pp.17901-17906.

Google Scholar

[9] Y.H. Ding, P. Zhang, Z.L. Long, Y. Jiang, D.S. Gao: J. Alloys Compd. Vol. 462 (2008), pp.340-342.

Google Scholar

[10] Jui-Chin Kuo, Shih-Chin Lee, Kuo-Chin Hsu, Shyh-Jiun Liu: Materials Letters. Vol. 62 (2008), pp.4594-4596.

Google Scholar

[11] Wei He, JiangfengQian, Yuliang Cao, Xinping Ai and Hanxi Yang: RSC Adv. Vol. 2(2012), p.3423–3429.

Google Scholar

[12] K.M. Shaju, G.V.S. Rao and B.V.R. Chowdari: ElectrochimActa. Vol. 48(2002), p.145–151.

Google Scholar

[13] EijiHosono, Tatsuya Saito, Junichi Hoshino: CrystEngComm. Vol. 15(2013), pp.2592-2597.

Google Scholar

[14] C.S. Johnson, N. Li, C. Lefief, J.T. Vaughey, M.M. Thackeray: Chem. Mater. Vol. 20(2008), p.6095.

Google Scholar

[15] Z. Lu,J.R. Dahn: Journal of ElectrochemicalSociety. Vol. 149 (2002), p.1454.

Google Scholar