A Novel Catalytic Activity of Ce-Zr-Mn-OX Mixed Oxides for Low Temperature Selective Catalytic Reduction of NO with NH3

Article Preview

Abstract:

A Ce-Zr-Mn-Ox (CZM) catalyst has been discovered for selective catalytic reduction of NOx with NH3 in the presence of O2. In this paper, The catalysts of CZM with 10~50 wt% MnO2 content and Ce-Zr-O2 (CZ) catalyst are prepared by hydrothermal synthesis method. The catalytic activity of CZM catalysts at different temperatures, different space velocities and different ratios of NH3/NO are studied. The results show that the catalyst of CZM with 40 wt% MnO2 content yields higher NO conversion at low temperature than others. This catalyst shows nearly 90% NOx conversion in a temperature range of 150°C~250 °C at a space velocity of 53000 h-1 .

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 864-867)

Pages:

635-639

Citation:

Online since:

December 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] H. Schneider, U. Scharf, A. Wokaun, A. Baiker, J. Catal. 146 (1994) 545-556.

Google Scholar

[2] L. Chen, J. Li, M. Ge, R. Zhu, Catalysis Today 153 (2010) 77.

Google Scholar

[3] Q. Zhang, C. Qiu, H. Xu, T. Lin, Z. Lin, M. Gong, Y. Chen, Catalysis Today 175 (2011) 171.

Google Scholar

[4] X. Chen, S. Gao, H. Wang, Y. Liu, Z. Wu, Catalysis Communications 14 (2011) 1.

Google Scholar

[5] X. Gao, Y. Jiang, Y. Fu, Y. Zhong, Z. Luo, K. Cen, Catalysis Communications 11 (2010) 465.

Google Scholar

[6] Costigan M, Cary R, Dobson S. Concise International Chemical Assessment. Geneva: WHO, 2001. 29.

Google Scholar

[7] G. Qi, R.T. Yang, Chemical Communications 7 (2003) 848-849.

Google Scholar

[8] Z. Wu, R. Jin, Y. Liu, H. Wang, Catalysis Communications 9 (2008) 2217-2220.

Google Scholar

[9] Y. Shen, S. Zhu, T. Qiu, S. Shen, Catalysis Communications 11 (2009) 20-23.

Google Scholar

[10] R.B. Jin, Y. Liu, Z.B. Wu, H.Q. Wang, T.T. Gu, Chemosphere 78 (2010) 1160-1166.

Google Scholar

[11] P.R. Ettireddy, N. Ettireddy, S. Mamedov, P. Boolchand, P.G. Smirniotis, Appl. Catal. B: Environ. 76 (2007) 123-134.

DOI: 10.1016/j.apcatb.2007.05.010

Google Scholar

[12] W. Xu, Y. Yu, C. Zhang, H. He, Catalysis Communications 9 (2008) 1453-1457.

Google Scholar

[13] G. Qi, R.T. Yang, R. Chang, Appl. Catal. B 51 (2004) 93-106.

Google Scholar

[14] X.F. Tang, Y.G. Li, X.M. Huang, Y.D. Xu, H.Q. Zhu, J.G. Wang, W.J. Shen, Appl. Catal. B 62 (2006) 265-273.

Google Scholar

[15] L. Lietti, Appl. Catal. B 10 (1996) 281-283.

Google Scholar

[16] Marbán G, Valdés-Solís T, Fuertes A B. J Catal 226 (2004) 138-140.

Google Scholar