Synthesis of Loaded Silver 4A Zeolite Molecular Sieve with Magnetic Cores of SiO2/(γ-Fe2O3- SiO2) for Demercuration

Article Preview

Abstract:

It is an effective solution to the problem of agglomeration using the magnetic composite SiO2/(γ-Fe2O3- SiO2) instead of traditional magnetic particles Fe3O4 as the core of molecular sieve. The traditional hydrothermal method was utilized by means of adding the magnetic composite particles SiO2/(γ-Fe2O3- SiO2) into the pre-made crystallization liquid. Then, a series of magnetic 4A zeolites with varying contents of SiO2/(γ-Fe2O3- SiO2) were synthesized under the condition of ultrasonic crystallization for 6 hours with the power of 100W and temperature of 70 °C . Afterwards, the characterization tests such as XRD,SEM,TG,IR were carried out; the final result showed that the performance of 4A zeolite molecular sieve with SiO2/(γ-Fe2O3- SiO2) is basically identical with the pure 4A zeolite molecular sieve. The absorption rate was 13.5927μg/g by using the 4A zeolite molecular sieve with SiO2/(γ-Fe2O3- SiO2) for the absorption of mercury. Key words: 4A zeolite molecular sieve; magnetic composite; silver loaded;Demercuration

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 881-883)

Pages:

1144-1148

Citation:

Online since:

January 2014

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] W. Huang, Y. Yang. Mercury in coal of China[J]. Coal Geology of China. 2002, (14): 37~41.

Google Scholar

[2] C. Zhang, G. Chen. Study on the occurrence and correlation between mercury and sulfur in coals form Liuzhi and Zunyi coal mines in Guizhou Province[J]. Journal of Fuel Chemistry and Technology , 2009 , 37(1): 1~5.

DOI: 10.1016/s1872-5813(09)60007-4

Google Scholar

[3] X. Fang, Y. Hong. Distribution and occurrence mode of mercury in some coals of GuiZhou province and its environmental impact [J]. Coal Geology & Exploration, 1998, 26: 12~16.

Google Scholar

[4] J. Zhou, X. Shi and H. Gao. Hg vapor adsorption property of modified roseites [J]. Journal of Power Engineering, 2006, 26(4): 558~563.

Google Scholar

[5] S. Meng, Y. Duan and L. Yang. Research development of mercury removal technologies for coal-fired flue gas [J]. Boiler Technology, 2008, 39(4) : 77~81.

Google Scholar

[6] M. Kuang, G. Yang. Study on mercury desorption from silver-loaded activated carbon fiber and activated carbon fiber [N]. Journal of Fuel Chemistry and Technology , 2008, 36(4): 468~474.

DOI: 10.1016/s1872-5813(08)60030-4

Google Scholar

[7] S. Wang, S. Xu. Preparation of SiO2 /(γ-Fe2O3 -SiO2) magnetic catalyst carrier [J]. Transactions of Nonferrous Metals Society of China, 2002, 15(11): 1761~1765.

Google Scholar

[8] J. Cao, D. Xing. Synthesis of magnetic 4A zeolite at ultrasonic condition [J]. Acta Physico-Chimica Sinica, 2007, 23(12): 1893~1898.

Google Scholar