Synthesis of Mesoporous Molecular Sieve MCM-41 and its Adsorption Behavior for Rhodamine B

Zeng He Li; Zhen Cui Wang; Ge Li; Yuan Can Liu

doi:10.4028/www.scientific.net/AMR.893.658

Paper Titles

The Cutting Residual Stress Included in the Surface Integrity
p.638

Influence of the Intermediate Annealing on Deformation Ability of the Cold Rolled Ring
p.644

Effect on the Grinding Performance by the Different Elements of the Auxiliary Material
p.649

Influence of Minimum Quantity Lubrication on Cutting Force and Tool Wear during Machining of GH4169
p.653

Synthesis of Mesoporous Molecular Sieve MCM-41 and its Adsorption Behavior for Rhodamine B
p.658

Design of the Face Structure of the Grinding-Driller Based on Deform-3D
p.664

Calculation Method for Interference Value in Metal Joining Structure
p.668

Simulation of HDIs Behaviors in the Plasma Arc Cold Hearth Melting Process
p.672

Fabrication of Polymer Micro-Patterns by Transient Thermolithography with Thickness Control
p.679

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 893Synthesis of Mesoporous Molecular Sieve MCM-41 and...

Synthesis of Mesoporous Molecular Sieve MCM-41 and its Adsorption Behavior for Rhodamine B

Abstract:

In this study, MCM-41 was synthesized by hydrothermal method, using non-toxic sodium metasilicate nonahydrate as the silicon source, cetyl trimethyl ammonium bromide (CTAB) as template, and sulfuric acid as the pH value adjustment agent. The effects of ratio of template agent to silicon source, pH value, crystallization temperature and crystallization time on the yield and crystallization of MCM-41 were investigated. MCM-41 was then characterized by XRD, FTIR, SEM, TEM and N₂ adsorption-desorption testing techniques. Rhodamine B adsorption studies were carried out to study the effects of pH value and reaction time on the adsorption properties of MCM-41. The resulting MCM-41 had smooth surface with a pore size of 3-4nm and an average diameter particle of about 5μm. It had high specific surface area up to 784m²/g, thus adsorption rate of MCM-41 for rhodamine B obtained 93% when pH=3, t=15min. The reaction fitting curve of the Lagergren first order reaction model was lg (q_e-q_t) =-0.00586-0.803t, R² = 0.97582.

You might also be interested in these eBooks

Advanced Materials and Engineering Materials III

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 893)

Pages:

658-663

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.893.658

Citation:

Cite this paper

Online since:

February 2014

Authors:

Zeng He Li, Zhen Cui Wang, Ge Li*, Yuan Can Liu

Keywords:

Adsorption, Hydrothermal Method, MCM-41, Mesoporous Molecular Sieve, Rhodamine B (RhB)

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] F. Ghorbani, H. Younesi , Z. Mehraban, M.S. Celik ,A. A. Ghoreyshi, M. Anbia. Preparation and characterization of highly pure silica from sedge as agricultural waste and its utilization in the synthesis of mesoporous silica MCM-41.J. Journal of the Taiwan Institute of Chemical Engineers . 44(2013).

DOI: 10.1016/j.jtice.2013.01.019

Google Scholar

[2] B. Boukoussa , R. Hamacha, A. Morsli, A. Bengueddach. Adsorption of yellow dye on calcined or uncalcined Al-MCM-41 mesoporous materials.J. Arabian Journal of Chemistry. 07(2013): 01–09.

DOI: 10.1016/j.arabjc.2013.07.049

Google Scholar

[3] D. Carriazo, C. Domingo, C. Martı´n, V. Rives. PMo or PW heteropoly acids supported on MCM-41 silica nanoparticles: Characterisation and FT-IR study of the adsorption of 2-butanol.J. Journal of Solid State Chemistry. 181(2008): 2046– (2057).

DOI: 10.1016/j.jssc.2008.05.004

Google Scholar

[4] O. Gok，A. S. ozcan，A. ozcan. Adsorption kinetics of naphthalene onto organo-sepiolite from aqueous solutions. J. Desalination，220(2008)：96-107.

DOI: 10.1016/j.desal.2007.01.025

Google Scholar