Growth of Porous Alumina Layer and Cerium Sealing of Al7xxx/SiC Composite for Structural Lightweight Alloy Corrosion Resistant Application

Abstract:

AMC (Aluminum Matrix Composite) as a main material for automotive and aircraft applications has the keyadvantage that islighter thanaluminumalloys. So, it can be ascertained that fuel comsumption forthoseapplicationswill be reduced. However, AMC materials are generally suceptible to galvanic corrosion due to galvanic reaction between aluminum matrix and reinforcement, and the formation of microstructure at matrix/reinforcement interface as well. Anodizing is the most effective surface modification method in order to protect AMCs surfaces. This process produces porous anodic coating which has the characteristics of high corrosion resistance and hardness layer. However, the presence of reinforcement particles in AMC hinders the initiation and growth of the protective oxide layer by forming cavities and micro crack. Therefore cerium sealing has been done to remedy the poor anodic film in order to further enhance the corrosion resistance in aggressive circumstances. The material studied in this research was AMC Al7xxx/SiC. Anodizing process were conducted in H₂SO₄ solution at current densities 15, 20, and 25 mA/cm² at 0°C for 30 minutes. Subsequently, continuedwithelectro lesssealinginCeCl3.6H₂O+H₂O₂ solutionat room temperature atpH9 for 30 minutes. The morphologies of anodic coating and sealing layer were examined by means of FE-SEM, the corrosion resistance of composites was estimated in a 3.5 wt.% NaCl solution by potentiodynamic polarization test. Coating process conducted by anodizing and cerium sealing in various of anodizing current densities at 0°C results in protective layers which lead to the decreasing of corrosion rate and current density up to four orders magnifications than that of bare and anodizedAl7xxx/SiCcomposite.

• Periodical: Advanced Materials Research (Volume 911)
• Pages: 55-59
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.911.55
• Online since: March 2014
• Authors: Vika Rizkia*, Badrul Munir, Johny Wahyuadi Soedarsono, Bambang Suharno, Andi Rustandi
• Keywords: Aluminum Matrix Composite (AMC), Anodizing, Cerium Sealing, Corrosion

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