Physical Absorption of CO2 Capture: A Review

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Removal of CO2 had been one of the main issues facing in worldwide. Intensive researches are still going on to effectively reduce CO2 at low cost. Physical absorption is one of the well-established technologies used to removal CO2 from other gases. The physical absorption process is simple; whereby it contains only one gas liquid contactor and a series of flash tank to regenerate solvent. The CO2 will be absorbed in the physical solvent in the high pressure gas liquid contactor and flashed out in the medium and low pressure flash tank. The advantage of using physical solvent is that the CO2 is absorbed without any chemical reaction involved, thus it can be flashed out easily by reducing the pressure, passing inert gas through the solvent and mild thermal regeneration. The physical absorption is the best operated at high pressure and low temperature as the solubility of CO2 in the solvent is high at the particular condition. Researches carried out currently are focusing on solvent development, absorption and desorption process development and mathematical modeling.

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134-143

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Figueroa, J.D., T. Fout, S. Plasynski, H. McIlvried, and R.D. Srivastava, Advances in CO2 capture technology—The U.S. Department of Energy's Carbon Sequestration Program, International Journal of Greenhouse Gas Control. 2(2008) 9-20.

DOI: 10.1016/s1750-5836(07)00094-1

Google Scholar

[2] Karimi, M., M. Hillestad, and H.F. Svendsen, Capital costs and energy considerations of different alternative stripper configurations for post combustion CO2 capture, Chemical Engineering Research and Design. 89(2011) 1229–1236.

DOI: 10.1016/j.cherd.2011.03.005

Google Scholar

[3] Yokozeki, A., M.B. Shiflett, C.P. Junk, L.M. Grieco, and T. Foo, Physical and chemical absorptions of carbon dioxide in room-temperature ionic liquids, J Phys Chem B. 112(2008) 16654-63.

DOI: 10.1021/jp805784u

Google Scholar

[4] Grande, C.A. and A.E. Rodrigues, Electric Swing Adsorption for CO2 removal from flue gases, International Journal of Greenhouse Gas Control. 2(2008) 194-202.

DOI: 10.1016/s1750-5836(07)00116-8

Google Scholar

[5] Wen, C., X. Cao, Y. Yang, and J. Zhang, Supersonic swirling characteristics of natural gas in convergent-divergent nozzles, Petroleum Science. 8(2011) 114-119.

DOI: 10.1007/s12182-011-0123-3

Google Scholar

[6] Nexant Inc., Survey and Down-Selection of Acid Gas Removal Systems for the Thermochemical Conversion of Biomass to Ethanol with a Detailed Analysis of an MDEA System Alliance for Sustainable Energy San Francisco, California (2009).

DOI: 10.2172/1013266

Google Scholar

[7] Olajire, A.A., CO2 capture and separation technologies for end-of-pipe applications - A review, Energy. 35(2010) 2610-2628.

DOI: 10.1016/j.energy.2010.02.030

Google Scholar

[8] Nguyen, D.N., Carbon Dioxide Geological Sequestration: Technical and Economic Reviews, in SPE/EPA/DOE Exploration and Production Environmental Conference, Society of Petroleum Engineers Inc.: San Antonio, Texas, U.S.A. (2003).

Google Scholar

[9] Abdi, M.A. Design and Operations of Natural Gas Sweetening Facilities. in Workshop for the 2nd Iranian Gas Forum. Iran, (2008).

Google Scholar

[10] Iranian Ministry of Petroleum, Engineering Standard for Process Design of Gas Treating Units. (1997).

Google Scholar

[11] Newman, S.A., Acid and sour gas treating process, (1985).

Google Scholar

[12] Kelly, Thambimuthu, M. Soltanieh, J.C. Abanades, Z. Abu-Ghararah, and T. Yashima, Capture of CO2, IPCC Special Report on Carbon dioxide Capture and Storage. (2005).

Google Scholar

[13] Kierzkowska-Pawlak, H. and A. Chacuk, Pressure swing absorption of carbon dioxide in physical solvents. Environmental Engineering III. Vol. 35. London: Taylor & Francis Group, (2009).

DOI: 10.1201/b10566-8

Google Scholar

[14] Ross, F.P. and K.T. Cuellar, Economical option for CO2/Methan separation in produced gas containing a high CO2 fraction. (2009).

Google Scholar

[15] Kohl, A.L. and F.E. Miller, Process for Carbon Dioxide Absorption, U.S. Patent, Editor. (1960).

Google Scholar

[16] Bucklin, R.W. and R.L. Schendel, Comparison of Fluor Solvent and Selexol Processes Energy Progress 4(1984) 137-142.

Google Scholar

[17] Henni, A., P. Tontiwachwuthikul, and A. Chakma, Solubilities of Carbon Dioxide in Polyethylene Glycol Ethers, The Canadian Journal of Chemical Engineering. 83(2005) 358-361.

DOI: 10.1002/cjce.5450830224

Google Scholar

[18] Rayer, A.V., A. Henni, and P. Tontiwachwuthikul, High Pressure Physical Solubility of Carbon Dioxide (CO2) in Mixed Polyethylene Glycol Dimethyl Ethers (Genosorb 1753), The Canadian Journal of Chemical Engineering. 9999(2011) 1-8.

DOI: 10.1002/cjce.20615

Google Scholar

[19] Gui, X., Z. -G. Tang, and W. -Y. Fei, Solubility determination of CO2 in physical solvents under high pressure, Huaxue Gongcheng/Chemical Engineering (China). 39(2011) 55-58.

Google Scholar

[20] Blanc, C., J. -Y. Chenard, J. -J. Delpuech, and O. Oliveau, Physical Solvent Absoprtion of Carbon Dioxide and Hydrogen Sulphide for the Deacidification of Industrial Gases Mixtures, U.S. Patent, Editor. (1979).

Google Scholar

[21] Pan, Y. -C. and E.L. Stogryn, Process for the Removal of Acid Gases From Hydrocarbon Gases Containing The Same, U.S. Patent, Editor. (1984).

Google Scholar

[22] Netzer, D. and R.R. Huebel, Carbon Dioxide Hydrocarbons Separation Process, U.S. Patent, Editor. (1986).

Google Scholar

[23] Jou, F.Y., R.D. Deshmukh, F.D. Otto, and A.E. Mather, Solubility of H2S, CO2 and CH4 in N-formyl morpholine, Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 85(1989) 2675-2682.

DOI: 10.1039/f19898502675

Google Scholar

[24] Heintz, Y.J., L. Sehabiague, B.I. Morsi, K.L. Jones, and H.W. Pennline, Novel Physical Solvents for Selective CO2 Capture from Fuel Gas Streams at Elevated Pressures and Temperatures, Energy & Fuels. 22(2008) 3824–3837.

DOI: 10.1021/ef800091e

Google Scholar

[25] Gui, X., Z. Tang, and W. Fei, CO2 Capture with Physical Solvent Dimethyl Carbonate at High Pressures, Journal of Chemical & Engineering Data. 55(2010) 3736–3741.

DOI: 10.1021/je1002708

Google Scholar

[26] Miller, M.B., W. Bing, D.R. Luebke, and R.M. Enick, Solid CO2-philes as potential phase-change physical solvents for CO2, The Journal of Supercritical Fluids. 61(2011) 212-220.

DOI: 10.1016/j.supflu.2011.09.003

Google Scholar

[27] Meissner, Process for Purifrication of Gas Stream, U.S. Patent, Editor. (1982).

Google Scholar

[28] Albiol, I.B., Process for treating natural gas, United States Patent. (1985).

Google Scholar

[29] Hemmings, J.W., P. Allan, and G.M. O'Shaughnessy, Purification of Gases, U.S. Patent, Editor. (1991).

Google Scholar

[30] Mak, J., D. Wierenga, D. Nielsen, and C. Graham, New Physical Solvent Treating Configurations for Offshore High Pressure CO2 Removal in Offshore Technology Conference Houston, Texas (2003).

DOI: 10.4043/15354-ms

Google Scholar

[31] Mak, J., Configuration and Methods of High Pressure Acid Gas Removal in the Production of Ultra-Low Sulfur Gas, WO Patent WO/2011/102, 830. (2011).

Google Scholar

[32] Timminns, C., Templeman, J. Joseph, Hodrien, and R. Chirstopher, Gas separation by physical absorption, E.P. Office, Editor. (1981).

Google Scholar

[33] Lechnick, W.J., L.A. Davis, M.R. Van de Cotte, and J.P. Brady, Use of Solvent Stream as Motive Fluid in Ejector Unit for Regenerating Solvent for Absorption Unit, United States Patent Application Publication. (2008).

Google Scholar

[34] Kierzkowska-Pawlak, H., Pressure swing absorption of carbon dioxide in n-methyl-2-pyrrolidone solutions, Polish Journal of Chemical Technology. 9(2007) 106-109.

DOI: 10.2478/v10026-007-0039-2

Google Scholar

[35] Ranke, G. and H. Weiss, Multiple Temperature Level Regeneration of CO2 From Physical Solvent, U.S. Patent, Editor. (1986).

Google Scholar

[36] Timminns, C. and K.R. Tart, High Pressure Physical Absorption Process for Use in Carbon Capture in Energy Production Processes, United States Patent Application Publication. (2009).

Google Scholar

[37] Kelly, R.M., R.W. Rousseau, and J.K. Ferrell, Design of Packed, Adiabatic Absorbers: Physical Absorption of Acid Gases in Methanol, Ind. Eng. Chem. Process Des. Dev. 23(1984) 102-109.

DOI: 10.1021/i200024a017

Google Scholar

[38] Evren, V. and A.R. Ozdural, A new technique for the determination of mass transfer coefficients in packed column for physical gas absorption systems, The Chemical Engineering Journal. 57(1995) 67-71.

DOI: 10.1016/0923-0467(94)02864-7

Google Scholar

[39] Zhang, G.D., W.F. Cai, C.J. Xu, and M. Zhou, A general enhancement factor model of the physical absorption of gases in multiphase systems, Chemical Engineering Science. 61(2006) 558 - 568.

DOI: 10.1016/j.ces.2005.07.035

Google Scholar

[40] Heil, S., C. Brunhuber, K. Link, J. Kittel, and B. Meyer. Dynamic Modelling of CO2-removal units for an IGCC power plant. in Proceedings 7th Modelica Conference. Como, Italy: The Modelica Association, (2009).

DOI: 10.3384/ecp09430021

Google Scholar

[41] Boributh, S., S. Assabumrungrat, N. Laosiripojana, and R. Jiraratananon, A modeling study on the effects of membrane characteristics and operating parameters on physical absorption of CO2 by hollow fiber membrane contactor, Journal of Membrane Science. 380(2011).

DOI: 10.1016/j.memsci.2011.06.029

Google Scholar