Hydrogen Adsorption Capacity Investigation of Ni-Co-Al Mixed Oxides

M. Abdus Salam; Suriati Sufian

doi:10.4028/www.scientific.net/AMR.917.360

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Hydrogen Adsorption Capacity Investigation of Ni-Co-Al Mixed Oxides
p.360

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 917Hydrogen Adsorption Capacity Investigation of...

Hydrogen Adsorption Capacity Investigation of Ni-Co-Al Mixed Oxides

Abstract:

Micro-mesoporous mixed oxides containing nickel, cobalt and aluminum have been synthesized using conventional coprecipitation method. FESEM and HRTEM analyses demonstrated the flower and hexagonal plate-like nanostructured of mixed oxides. Different mixed oxide formation, homogenous metal dispersion, textural properties were investigated using XRD, ICP-MS and BET (N₂ adsorption-desorption) techniques. nanostructured mixed oxides exhibited 2.6 wt% hydrogen adsorption that were studied using temperature programmed reduction-adsorption-desorption (H₂-TPR/TPD) and thermogravimetric and differential thermal analysis (TGA-DTA) techniques. Investigation corresponds that morphologies, textural properties and surface energy of mixed oxides are important in hydrogen adsorption.

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Advanced Materials Research (Volume 917)

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360-364

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https://doi.org/10.4028/www.scientific.net/AMR.917.360

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Online since:

June 2014

Authors:

M. Abdus Salam, Suriati Sufian

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Cationic Radius, Coprecipitation, Hydrogen Capacity, Mesoporous, Mixed Oxides

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References

[1] D. Zhao D, Yuan D, Zhou H C, The current status of hydrogen storage in metal-organic frameworks. Energy Environ. Sci. 1 (2008) 222-227.

DOI: 10.1039/b808322n

Google Scholar

[2] M. A Salam, S. Sufian, Y. Lwin, Hydrogen adsorption study on mixed oxides using the density functional theory, J. Phys. Chem. Solids 74 (2013)558-564.

DOI: 10.1016/j.jpcs.2012.12.004

Google Scholar

[3] L. Jalowiecki-Duhamela, J. Carpentiera, A. Ponchelb, Catalytic hydrogen storage in cerium nickel and zirconium (or aluminium) mixed oxides Int. J. Hydrogen Energy 32(2007) 2439-2444.

DOI: 10.1016/j.ijhydene.2006.10.056

Google Scholar

[4] F. Bergaya, B.K.G. Theng, G. Lagaly, Handbook of Clay Science, Developments in Clay Science, Vol. 1, chapter 3. 1, Elsevier, Amsterdam, 2006, p.1224.

DOI: 10.1016/s1572-4352(05)01015-9

Google Scholar

[5] Z. Yong, V. Mata, A.E. Rodrigues, Adsorption of carbon dioxide onto Hydrotalcite-like compounds (HTlcs) at high temperatures, Ind. Eng. Chem. Res. 40(2001) 204-209.

DOI: 10.1021/ie000238w

Google Scholar

[6] P. X. Zhi, J. Zhang , M. O. Adebajo , H. Zhang , C. Zhou, Catalytic applications of layered double hydroxides and derivatives, Applied Clay Science 53(2011)139-150.

DOI: 10.1016/j.clay.2011.02.007

Google Scholar

[7] S.D. Ribet, B. Tichit, B. Coq, F. Ducourant, Synthesis and activation of Co–Mg–Al layered double hydroxides J. Solid State Chem. 142(1999) 382-88.

DOI: 10.1006/jssc.1998.8053

Google Scholar

[8] N.A. Hermes, M. A. Lansarin, O. W. Perez-Lopez, Catalytic decomposition of methane Over M–Co–Al catalysts (M = Mg, Ni, Zn, Cu), Catal. Lett. 141(2011)1018.

DOI: 10.1007/s10562-011-0611-5

Google Scholar

[9] L. Chmielarz, P. Kustrowski, A. Rafalska-Lasocha and R. Dziembaj, Influence of Cu, Co and Ni cations incorporated in brucite-type layers on thermal behaviors of hydrotalcites and reducibility of the derived mixed oxide systems, Thermochim. Acta 395 (2003).

DOI: 10.1016/s0040-6031(02)00214-9

Google Scholar