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A New POM-Based Supramolecular Compound: Synthesis, Structure and Adsorptive Property of [Cu(phen)2]3[W6O19]

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Abstract:

A POM - based organice - inorganic hybrid compound with the chemical formula of[Cu (phen)2]3[W6O19] (phen = 1,10-phenanthroline) (1) has been hydrothermally synthesized andstructurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic space group C2/c with a =18.319(4) Å, b = 17.311(4) Å, c = 22.248(4) Å, β = 112.40(3) o, V = 6523(2) Å3, Z = 4, R1 = 0.0448, and wR2 =0.1218. Compound 1 consists of the [W6O19]3- building blocks and [Cu (phen)2]+ metal organic cationic moieties, which are packed together via the extensive hydrogen-bonding interactions to form a three-dimensional supramolecular framework. The adsorption of methylene blue (MB) under UV irradiation with 1 as the heterogeneous adsorbent has been investigated, showing a good adsorptive property of 1 for MB degradation.

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Periodical:

Advanced Materials Research (Volumes 919-921)

Pages:

2013-2016

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.919-921.2013

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Online since:

April 2014

Authors:

Ya Bing Liu*, Hong Jie Wang, Hong Kai Zhao

Keywords:

Adsorptive Property, Degradation, Hydrothermal Synthesis, Polyoxometalate

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] J.M. Lehn: Supramolecular Chemistry (VCH, New York 1995).

Google Scholar

[2] F. Vögtle: Supramolecular Chemistry (Wiley Chicester 1991).

Google Scholar

[3] M. Lehn: Comprehensive Supramolecular Chemistry (Pergamum, New York 1996).

Google Scholar

[4] J.M. Lehn. Angew. Chem. Int. Ed. Engl., 29 (1990), 1304.

Google Scholar

[5] C.N.R. Rao, Natarajan, R. Vaidhyanathan. Angew. Chem. Int. Ed. Engl., 43 (2004), 1466.

Google Scholar

[6] O.M. Yaghi, M. ơkeeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi, J. Kim, Nature, 23 (2003), 705.

Google Scholar

[7] X.Y. Yu, X.B. Cui, J. Lu, Y.H. Luo, H. Zhang, W.P. Gao, J. Solid State Chem., 209 (2014), 97.

Google Scholar

[8] G. Yan, X. Wang, Y.Y. Ma, X. Cheng, Y.H. Wang, Y.G. Li, Solid State Scinces, 17 (2013), 146.

Google Scholar

[9] A.J. Bridgeman, G. Cavigliasso, Inorg. Chem., 41 (2002), 1761.

Google Scholar

[10] D. Altermatt, I.D. Brown, Acta Crystallogr. B, 41 (1985), 240.

Google Scholar

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