Application of Au Nanoparticles–AgCl@Polypyrrole Hybrid Material to Amperometric Biosensor

Abstract:

AgCl@polypyrrole(PPy) nanocomposites were synthesized through in situ chemical oxidation polymerization by using poly(vinylpyrrolidane) (PVP) as dispersant, and some Au colloid were prepared by using KBH4 as reductant and sodium citrate as stabilizer, then the Au nanoparticles-AgCl@PPy hybrid material was formed by physical chemical reaction. Fourier transform infrared spectrometer (FTIR) and electron dispersive spectrometer (EDS) data suggested that the hybrid material were composed of Au, AgCl and PPy. An amperometric glucose biosensor was fabricated by adsorbing glucose oxidase (GOx) to an Au nanoparticles-AgCl@PPy hybrid material modified platinum electrode. The biosensor exhibited a super highly sensitive response to H2O2.

• Periodical: Advanced Materials Research (Volume 92)
• Pages: 23-28
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.92.23
• Online since: January 2010
• Authors: Xiang Zhong Ren, Li Zhang, Ying Kai Jiang, Pei Xin Zhang, Jian Hong Liu, Qian Ling Zhang
• Keywords: AgCl@polypyrrole, Au Nanoparticle, Glucose Biosensor, Hybrid Material

References

[1] D. Olea, O. Viratelle, C. Faure.: J. Biosensors and Bioelectronics. 23 (2008), p.788.

[2] W. Yan, X.M. Feng, X.J. Chen, W.H. Hou, J.J. Zhu.: J. Biosens. Bioelectron. 23 (2008), p.925.

[3] H. Shirakawa, E.J. Louis, A.G. MacDiarmid, C.K. Chiang, A.J. Heeger.: J. Chem. Soc., Chem. Commun. 16 (1977), p.577.

[4] L. Liang, J. Liu, C.F. Windisch, G.J. Exarhos, Y. Lin.: J. Angew. Chem. Int. Ed. 41 (2002), p.3665.

[5] S.C. Huang, I.J. Ball, R.B. Kaner.: J. Macromolecules. 31(1998), p.5456.

[6] J. Huang, S. Virji, B.H. Weiller, R.B. Kaner.: Polyaniline Nanofibers: J. Am. Chem. Soc. 125 (2003), p.314.

DOI: 10.1021/ja028371y

[7] G.X. Wang, L. Yang, Y. Chen, J.Z. Wang, S. Bewlay H.K. Liu.: J. Electrochim. Acta, 50 (2005), p.4649.

[8] X.Z. Ren, Q. Zhao, J.H. Liu, X. Liang, Q.L. Zhang, P.X. Zhang, Z.K. Luo, Y. Gu.: J. Nanosci. Nanotechnol. 8(2008), p.2643.

[9] X.Z. Ren, P.X. Zhang, J.H. Liu, Q.L. Zhang. Advanced Materials Research. 58 (2009), p.15.

[10] H. Ben Fredj, S. Helali, C. Esseghaier, L. Vonna, L. Vidal,A. Abdelghani.: J. Talanta. 75 (2008), p.740.

DOI: 10.1016/j.talanta.2007.12.034

[11] I. Willner, R. Baron, B. Willner.: J. Adv. Mater. 18 (2006), p.1109.

[12] D. Du, S.Z. Chen, J. Cai, A.D. Zhang.: J. Biosens. Bioelectron. 23 (2007), p.130.

[13] J.M. Gong, L.Y. Wang, L.Z. Zhang.: Biosensors and Bioelectronics. 24 (2009), p.2285.

[14] N. Zhou, J. Wang, T. Chen, Z. Yu, G. Li.: J. Anal. Chem. 78 (2006), p.5227.

[15] Y. Xian, Y. Hu, F. Liu, Y. Xian, H. Wang, L. Jin.: J. Biosens. Bioelectron. 21 (2006), p. (1996).