Investigation on the Single-Ion Conductivity of PAN/Li-MMT Nanocomposite

Mitch Irene Kate N. Galvan; Junierose C. Diamante; Leslie Joy L. Diaz

doi:10.4028/www.scientific.net/AMR.925.344

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 925Investigation on the Single-Ion Conductivity of...

Investigation on the Single-Ion Conductivity of PAN/Li-MMT Nanocomposite

Abstract:

In this study, PCNs were synthesized using Li impregnated montmorillonite (Li-MMT) in PAN matrix to promote single-ion conduction. Ion exchange resulted to 4782.5 ± 112.5 ppm Li⁺ ions impregnated to MMT. Then, Li-MMT was incorporated to PAN via solution intercalation method. The investigation on the structure of PAN/Li-MMT nanocomposites showed that PAN was partially intercalated with Li-MMT. Moreover, electrical conductivity measurements showed that the conductivity for PCN with 15wt% Li-MMT was 3.58x10^-8 S/cm.

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Periodical:

Advanced Materials Research (Volume 925)

Pages:

344-348

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.925.344

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Online since:

April 2014

Authors:

Mitch Irene Kate N. Galvan*, Junierose C. Diamante, Leslie Joy L. Diaz

Keywords:

Nanoclay, Polyacrylonitrile (PAN), Polymer Composite Electrolyte (PCE), Polymer-Clay Nanocomposite (PCN), Single-Ion Conduction

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References

[1] S. Kim and S.J. Park, Preparation and ion-conducting behaviors of poly(ethylene oxie)-composite electrolytes containing lithium montmorillonite, Solid State Ionics, no. 178, pp.973-979, (2007).

DOI: 10.1016/j.ssi.2007.03.008

Google Scholar

[2] M. Kurian, M.E. Galvin, P.E. Trapa, D.R. Sadoway, and A.M. Mayes, Single-ion conducting polymer-silicate nanocomposite electrolytes for lithium battery applications, Electrochimica Acta, no. 50, pp.2125-2134, (2005).

DOI: 10.1016/j.electacta.2004.09.020

Google Scholar

[3] M. Alexandre and P. Dubios, Polymer-layered silicate nanocomposites: preparation, properties and uses of a newclass of materials, Materials Science and Engineering, no. 28, pp.1-63, (2000).

DOI: 10.1016/s0927-796x(00)00012-7

Google Scholar

[4] Boone B Owens, Solid state electrolytes: overview of materials and applications during the last third of the Twentieth Century, Journal of Power Sources, no. 90, pp.2-8, (2000).

DOI: 10.1016/s0378-7753(00)00436-5

Google Scholar

[5] T. Yu et al., Novel polyacrylonitrile/Na-MMT/silica nanocomposite: Co-incorporation of two different form nano materials into polymer matrix, Composites Science and Technology, no. 67, pp.3219-3225, (2007).

DOI: 10.1016/j.compscitech.2007.04.004

Google Scholar

[6] Y.T. Chen, Y.C. Chuang, J.H. Su, H.C. Yu, and Y.W. Chen-Yang, High discharge capacity of solid composite polymer electrolyte lithium battery, Journals of Power Sources, no. 196, pp.2802-2809, (2011).

DOI: 10.1016/j.jpowsour.2010.11.058

Google Scholar

[7] Peter G. Bruce, James Evans, and Colin A. Vincent, Conductivity and transference number measurements on polymer electrolytes, Solid State Ionics, no. 28-30, pp.918-922, (1988).

DOI: 10.1016/0167-2738(88)90304-9

Google Scholar