Corrosion Inhibition of Gemini Surfactant for Copper in 3.5% NaCl

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A new gemini surfactant containing long chain alkyl ammonium headgroups have been used as corrosion inhinbitor for copper in 3.5% NaCl solution. The weight loss and electrochemical methods results showed that presence of inhibitor greatly decrease corrosion rate, gemini surfactant acted as an excellent corrosion inhibitor with inhibition efficiency greater than 96% at an optimum concentration of 30 mg·L-1. X-ray photoelectron spectroscopy reveals that the gemini surfactant molecules adsorb onto the copper surface through the two ammonium head groups (N+).

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June 2014

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[1] E.M. Sherif, S. -M. Park, Inhibition of copper corrosion in 3. 0% NaCl solution by N-Phenyl-1, 4-phenylenediamine, J. Electrochem. Soc. 152 (2005) B428-B433.

DOI: 10.1149/1.2018254

Google Scholar

[2] H.O. Curkovic, E.S. Lisac, H. Takenouti, The influence of pH value on the efficiency of imidazole based corrosion inhibitors of copper, Corros. Sci. 52 (2010) 398–405.

DOI: 10.1016/j.corsci.2009.09.026

Google Scholar

[3] T. Hoepner, S. Lattemann, Chemical impacts from seawater desalination plants -- a case study of the northern Red Sea, Desalination 152 (2003) 133-140.

DOI: 10.1016/s0011-9164(02)01056-1

Google Scholar

[4] A.L. Bacarella, J.C. Griess, The anodic dissolution of copper in flowing sodium chloride solutions between 25° and 175°, J. Electrochem. Soc. 120 (1973) 459-465.

DOI: 10.1149/1.2403477

Google Scholar

[5] S. Issaadi, T. Douadi, A. Zouaoui, S. Chafaa, Novel thiophene symmetrical Schiff base compounds as corrosion inhibitor for mild steel in acidic media, Corros. Sci. 53 (2011) 1484–1488.

DOI: 10.1016/j.corsci.2011.01.022

Google Scholar

[6] H. Ashassi-Sorkhabi, E. Asghari, Effect of hydrodynamic conditions on the inhibition performance of l-methionine as a green, inhibitor, Electrochim. Acta 54 (2008) 162–167.

DOI: 10.1016/j.electacta.2008.08.024

Google Scholar

[7] E.M. Sherif, R.M. Erasmus, J.D. Comins, Corrosion of copper in aerated synthetic sea water solutions and its inhibition by 3-amino-1, 2, 4-triazole, J. Colloid Interface Sci. 309 (2007) 470–477.

DOI: 10.1016/j.jcis.2007.01.003

Google Scholar

[8] H.W. Tian, W.H. Li, K. Cao, B.R. Hou, Potent inhibition of copper corrosion in neutral chloride media by novel non-toxic thiadiazole derivatives, Corros. Sci. 73 (2013) 281-291.

DOI: 10.1016/j.corsci.2013.04.017

Google Scholar

[9] M.A. Elmorsi, A.M. Hassanein, Corrosion inhibition of copper by heterocyclic compounds, Corros. Sci. 41 (1999) 2337-2352.

DOI: 10.1016/s0010-938x(99)00061-x

Google Scholar

[10] D. Asefi, M. Arami, N.M. Mahmoodi, Electrochemical effect of cationic gemini surfactant and halide salts on corrosion inhibition of low carbon steel in acid medium, Corros. Sci. 52 (2010) 794-800.

DOI: 10.1016/j.corsci.2009.10.039

Google Scholar

[11] L.G. Qiu, A.J. Xie, Y.H. Shen, Understanding the effect of the spacer length on adsorption of gemini surfactants onto steel surface in acid medium, Appl. Surf. Sci. 246 (2005) 1-5.

DOI: 10.1016/j.apsusc.2004.11.016

Google Scholar

[12] M.A. Hegazy, M. Abdallah, H. Ahmed, Novel cationic gemini surfactants as corrosion inhibitors for carbon steel pipelines, Corros. Sci. 52 (2010) 2897-2904.

DOI: 10.1016/j.corsci.2010.04.034

Google Scholar

[13] M.A. Hegazy, A novel Schiff base-based cationic gemini surfactants: Synthesis and effect on corrosion inhibition of carbon steel in hydrochloric acid solution, Corros. Sci. 51 (2009) 2610-2616.

DOI: 10.1016/j.corsci.2009.06.046

Google Scholar

[14] M.A. Quraishi, J. Rawat, Influence of iodide ions on inhibitive performance of tetraphenyl-dithia-octaaza-cyclotetradeca-hexaene (PTAT) during pickling of mild steel in hot sulfuric acid, Mater. Chem. Phys. 70 (2001) 95-99.

DOI: 10.1016/s0254-0584(00)00459-4

Google Scholar

[15] O. Olivares, N.V. Likhanova, B. Gomez, J. Navarrete, M.E. Llanos-Serrano, E. Arce, J.M. Hallen, Electrochemical and XPS studies of decylamides of a-amino acids adsorption on carbon steel in acidic environment, Appl. Surf. Sci. 252 (2006).

DOI: 10.1016/j.apsusc.2005.04.040

Google Scholar