Paper Titles

Effect of Cobalt Concentration on Bi_0.95Ba_0.05Fe_1-xCo_xO₃
p.85

Synthesis, Magnetic and Surface Properties of Reduced Graphene Oxide Supported Nickel Oxide Hybrid Nanomaterials
p.91

Study of Electronic and Magnetic Properties of Nitrogen Doped Graphene Oxide
p.97

Structural and Optical Properties of Nebulized Nickel Oxide Thin Films
p.103

Electrical Conductivity Properties of Nd₂O₃ Doped LiCl-PbO-ZnO Glass Ceramics
p.108

Synthesis of Cu₂O Nanospheres and Cubes: Their Structural, Optical and Magnetic Properties
p.114

Near-Field Scanning Optical Microscopy: Single Channel Imaging of Selected Gold Nanoparticles through Two Photon Induced Photoluminescence
p.118

Investigation of Optical Properties of ZnO/MnO₂, ZnO/TiO₂ and ZnO/MnO₂/TiO₂ Nanocomposites
p.123

Structural and Magnetic Properties of Ultrafine Magnesium Ferrite Nanoparticles
p.128

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 938Electrical Conductivity Properties of Nd2O3 Doped...

Electrical Conductivity Properties of Nd₂O₃ Doped LiCl-PbO-ZnO Glass Ceramics

Article Preview

Abstract:

xNd₂O₃-35LiCl-(30-x)PbO-35ZnO glasses (where x=0.1, 0.2, 0.3, 0.4 and 0.5 mol %) were prepared by melt quenching method and converted to glass ceramics by controlled crystallization processes. Glass and glass ceramic phases were confirmed by XRD. The electrical conductivity of these samples has been carried out as a function of frequencies at different temperature. Ac conductivity data of these glasses has been analyzed using a single power law. The exponents obtained from the power law fits is found to be in the range from 0.2 0.3 in these glass ceramics and shows moderate temperature dependence. The stretched exponent β also is seen to vary slightly with temperature. Scaling behavior also has been carried out using the reduced plots of conductivity and frequency. The time-temperature superposition of data points is found to be satisfactory indicating that the ion transport mechanism decreases with annealing temperature and increase with compositions studied. Activation energy (E_a) has been calculated for all the samples at different temperatures, is found to vary in the range of 0.4eV to 0.5eV.

You might also be interested in these eBooks

Nanomaterials: Science, Technology and Applications

Info:

Periodical:

Advanced Materials Research (Volume 938)

Pages:

108-113

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.938.108

Citation:

Cite this paper

Online since:

June 2014

Authors:

M. Sathish, B. Eraiah*

Keywords:

AC Conductivity, DC Conductivity, DSC, Glass Ceramics, X-Ray Diffraction (XRD)

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] M. Armand, J.M. Tarascon, Nature. 451 (2008) 652.

[2] M. El-Muraikhi, J. Non-Cryst. Solids. 40 (1980) 93.

[3] R. Prasada Rao, T.D. Tho, S. Adams, J. power. sources 189 (2009) 385.

[4] V.K. Deshpande, Phys. Educ. (July 1995) 107.

[5] R.G. Linford, Solid State Ionics. 28–30 (1) (1988) 83.

[6] T. Minami, J. Non-Cryst. Solids. 95/96 (1987) 107.

[7] C.A. Angell, Solid State Ionics 105 (1998) 15.

[8] P.W. Mcmillan, Glass Ceramics, Academic Press, New York, (1964).

[9] W.D. Kingery, Introduction to Ceramics, A Wiley –Inter science Publication, (1976).

[10] M.S. Meikhail, I.A. Gohar, A.A. Megahed, J. Appl. Phys. 26 (1993) 1125.

[11] J.E. Garbarczyk, L. Tykarski, J.L. Nowinski, Solid State Ionics. 154/155 (2002) 367.

[12] A.V. Deshpande, V.K. Deshpande, Solid State Ionics. 154 / 155 (2002) 433.

[13] Jie Fu, J. Am. Ceram. Soc. 83 (4) (2000) 1004.

[14] R.T. Johnson Jr., B. Morosin, M.L. Knotek, R.M. Biefeld, Phys. Lett. 54 A (5) (1975) 403.

[15] S. Fang, Solid State Ionics. 7 (1982) 37.

[16] C. Shixun, H. Yusheng, C. Liquan, Solid State Ionics. 45 (1991) 223.

[17] A.M. Sukeshini,K. Hariharan, Thehague (The Netherlands) (1993) 709 SSI 9.

[18] St. Adams, K. Hariharan, J. Maier, Solid State Phenomenon. 39/40(1994) 285.

[19] O. Furusawa, A. Kamiyama, T. Tsurui, Solid State Ionics. 179 (2008) 536.

[20] A.A. Soliman, S.A. Aly, H. Frhan, Y.M. Abo-Zeid, Radiat. Phys. Chem. 54 (1999)499.

[21] S. Muthupari, S. L. Raghavan, K. J. Rao, J. Phys. Chem. 100 (1996)4243.

[22] D.P. Almond, A.R. West, R.J. Grant, Solid. State. Commum. 44 (1982) 1277.

[23] D.P. Almond, G.K. Duncan, A.R. West, Solid. State. Ionics. 8 (1983) 159.

[24] D.P. Almond, C.C. Hunter, A.R. West, J. Mater. Sci. 19 (1984) 3236.

[25] P.J. Bray, (1996) In: Porai-Koshits. E (ed) The structure of glass, Consultant Bureau, New York.

[26] C.T. Moynihan, L.P. Boesch, B. L . Laberge, Phy Chem glasses. 14 (1973) 122.

[27] H.K. Patel, S.W. Martin, Phys Rev B. 45 (1992)10292.