Kinetics Model Comparison of Different Pre-Treated Sweet Sorghum Bagasse Pyrolysis

Article Preview

Abstract:

In order to find out the appropriate kinetic model for biomass pyrolysis, pyrolysis experiments of four samples (untreated biomass, HCl-washed, 3%KCl-treated and 10% KCl-treated) of sweet sorghum bagasse were performed by Thermogravimetry (TG) separately at different heating rates. The pyrolysis data was processed by the methods of Ozawa、Coats-Redfern integration and Achar-Brindley-Sharp differential, and the kinetic parameters were calculated. The results showed that the activation energy from deduced mechanism functions is more approach to the Ozawa’s than that from tentative mechanism functions, and the deduced mechanism functions can more realistically reflect the dynamic process four samples of sweet sorghum bagasse pyrolysis.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 953-954)

Pages:

230-234

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Piroska Szabó, et al. Journal of Analytical and Applied Pyrolysis, 36: 179-190, (1996).

Google Scholar

[2] Wu Chuangzhi, Ma Longlong. Modernization using technology of biomass energy [M]. Bingjing: Chemical Industry Press, (2003). In Chinese.

Google Scholar

[3] Ion V. Ion, Florin Popescu, Gina G. Rolea. J Therm Anal Calorim. 111: 1811-1815, (2013).

DOI: 10.1007/s10973-012-2552-7

Google Scholar

[4] Dongyu Chen, et al. WAC2012. (2012).

Google Scholar

[5] He Fang, et al. Journal of Solar Energy. 24(6): 771-775, (2003).

Google Scholar

[6] C. Li, Y. Yamamoto, et al. Journal of Thermal Analysis and Calorimetry. 95 (3): 991-997, (2009).

Google Scholar

[7] Jan Piskorz, et al. Journal of Analytical and Applied Pyrolysis, 46: 15 – 29, (1998).

Google Scholar

[8] Chen Dongyu, Liu Ronghou, Cai Junmeng. Transactions of the Chinese Society of Agricultural Engineering. 23(2): 188-194, (2007). In Chinese.

Google Scholar

[9] Ozawa T. Bulletin of the chemical society of Japan, 38: 1881-1886, (1965).

Google Scholar

[10] Achar B N. Proc. Int. Clay Conf, 1: 6, (1969).

Google Scholar

[11] Coats A W, Redern J.P. Nature(London), 1: 68, (1964).

Google Scholar

[12] Hu Rongzu, Shi Qizhen. Thermal analysis kinetics[M]. Bingjing: Science Press. 2001. In Chinese.

Google Scholar

[13] Lu Zhenrong, Yang Li. Thermochim. Acta. 1991, 188(1): 135-142.

Google Scholar

[14] Zhao Ming, et al. Transactions of the Chinese Society of Agricultural Engineering. 18(1): 107- 110, (2002). In Chinese.

Google Scholar

[15] Song CHC., et al. Journal of fuel chemistry and technology, 31(4): 311-315, (2003), In Chinese.

Google Scholar

[16] J. Guo, A.C. Lua. Biomass and Bioenergy, 20: 223–233, (2001).

Google Scholar