Radical Polymerizations of Optically Active Methacrylamides Having Oxazoline Moieties

Chao Yuan; Ying Bo Tao; Xiao Xiao Li; Xiao Meng Liu

doi:10.4028/www.scientific.net/AMR.955-959.732

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 955-959Radical Polymerizations of Optically Active...

Radical Polymerizations of Optically Active Methacrylamides Having Oxazoline Moieties

Abstract:

A novel type of chiral N-substituted methacrylamide derivatives bearing an oxazoline pendant (OPMAM) had been synthesized. Radical polymerization were carried out to produced corresponding polymers with high specific rotation in moderate yields. The polymerization characteristics and the chiroptical behavior of the resultant polymers have been examined in detail by using HPLC and CD and UV-vis spectra. The polymers showed relatively high molecular weights(Mn=5000-15000). The abolutely value of the specific rotation of poly(OPMAM)s basically increased with increasing the molecular weights.