Selective Hydrogenation of p-Chloronitrobenzene Catalyzed by FexOY@C Supported Pt-Catalyst

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Abstract:

FexOy@C nanocomposites were synthesized and used as carriers for depositing Pt nanoparticles. Catalytic properties of the nanocomposites were investigated for the hydrogenation of p-chloronitrobenzene at room temperature and balloon hydrogen pressure. The catalyst Pt/FexOy@C was extremely active for the hydrogenation of p-chloronitrobenzene. Completely conversion of p-chloronitrobenzene was achieved with a selectivity of 99.7 % in ethanol-water mixture in a reaction time of 40 min. Moreover, it can be reused four times without loss of any activity.

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Advanced Materials Research (Volumes 960-961)

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221-224

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] G.Y. Fan, and W.J. Huang: Chin. Chem. Lett., Vol. 25 (2014), p.359.

Google Scholar

[2] G.Y. Fan, W.J. Huang, C.Y. Wang, Nanoscale, Vol. 5 (2013), p.6819.

Google Scholar

[3] C. Antonetti, M. Oubenali, A.M. Raspolli Galletti, P. Serp and G. Vannucci: Appl. Catal. A: Vol. 421 (2012), p.99.

Google Scholar

[4] M. Oubenali, G. Vanucci, B. Machado, M. Kacimi, M. Ziyad, J. Faria, A. Raspolli‐Galetti, P. Serp: ChemSusChem, Vol. 4 (2011) , p.950.

DOI: 10.1002/cssc.201000335

Google Scholar

[5] X. Meng, H. Cheng, S. -i. Fujita, Y. Hao, Y. Shang, Y. Yu, S. Cai, F. Zhao, and M. Arai: J. Catal., Vol. 269 (2010), p.131.

Google Scholar

[6] G.Y. Fan, L. Zhang, H.Y. Fu, M.L. Yuan, R.X. Li, H. Chen, and X.J. Li, Catal. Commun., Vol. 11 (2010), p.451.

Google Scholar

[7] J. Zhang, Y. Wang, H. Ji, Y. Wei, N. Wu, B. Zuo, and Q. Wang:J. Catal., Vol. 229 (2005), p.114.

Google Scholar

[8] B. Zuo, Y. Wang, Q. Wang, J. Zhang, N. Wu, L. Peng, L. Gui, X. Wang, R. Wang, and D. Yu, J. Catal., Vol. 222 (2004), p.493.

Google Scholar

[9] Q. Yang, J. Zhang, L. Zhang, H. Fu, X. Zheng, M. Yuan, H. Chen, R. Li, Catal. Commun., Vol. 40 (2013), p.37.

Google Scholar

[10] G. Yu, B. Sun, Y. Pei, S. Xie, S. Yan, M. Qiao, K. Fan, X. Zhang, B. Zong, J. Am. Chem. Soc., 132 (2009) 935-937.

Google Scholar