Decolorization of Methylene Blue by Photocatalyst in the Ag3PO4-AgI System

Article Preview

Abstract:

The co-effect of PO43- and I- on the formation of a heterosturucture photocatalyst in the Ag3PO4-AgI system was studied by the co-precipitation method between AgNO3 and the precipitating agent. The precipitating agent was prepared by varying the mole ratios between Na2HPO4 and KI. At 10 mol.% KI, the product showed the mixed phase between Ag3PO4 and un-identified phase. For 30 - 90 mol.% KI, the un-identified phase and AgI were detected in the x-ray diffraction patterns. The un-identified phase strongly adsorbed the methylene blue dye. The product prepared from 30 mol.% KI had the highest content of un-identified phase and also showed the highest degree of decolorization in the dark. The photocatalytic properties of products in this system were confirmed by the decolorization of methylene blue under visible illumination.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

29-32

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J.M. Herrmann, Heterogeneous photocatalysis: state of the art and present applications, Top. Catal. 34 (2005) 49-65.

Google Scholar

[2] Y.P. Bi, S.X. Ouyang, N. Umezawan, J.Y. Cao, J.H. Ye, Facet Effect of Single-Crystalline Ag3PO4 Sub-microcrystals on Photocatalytic Properties, J. Am. Chem. Soc. 133 (2011) 6490-6492.

DOI: 10.1021/ja2002132

Google Scholar

[3] J. Cao, B. Luo, H. Lin, B. Xu, S. Chen, Visible light photocatalytic activity enhancement and mechanism of AgBr/Ag3PO4 hybrids for degradation of methyl orange, J. Hazard. Mater. 217-218 (2012) 107-115.

DOI: 10.1016/j.jhazmat.2012.03.002

Google Scholar

[4] N. Machida, S. Nishida, T. Shigematsu, H. Sakai, M. Tatsumisago, T. Minami: Mechano chemical synthesis of a silver ion conductor in the system AgI–Ag3PO4, Solid State Ionics 136-137 (2000) 381-386.

DOI: 10.1016/s0167-2738(00)00488-4

Google Scholar

[5] Z. Yi, J. Ye, N. Kikugawa, T. Kako, S. Ouyang, H. Stuart-Williams, H. Yang, J. Cao, W. Luo, Z. Li, Y. Liu, R.L. Withers, An orthophosphate semiconductor with photooxidation properties under visible-light irradiation, Nature Mater. 9 (2010).

DOI: 10.1038/nmat2780

Google Scholar