A Simple Method for Large-Scale Synthesis of Nano-Sized Zinc Sulfide

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Abstract:

nanosized zinc sulfide (ZnS) is a special property semiconductor material widely used in many applications such as catalyst, light emitting diode, transistor, gas sensors, biosensors, UV-light sensors, and photovoltaic cell. The wet chemical method is a simple and low-cost method to prepare nanosized zinc sulfide. However, the wet chemical reaction using sodium sulfide without surfactant or template has rarely been reported. In the present work nanosized zinc sulfide particles were synthesized by simple wet chemical reaction method at room temperature and without any surfactant. The influence of sulfur source, sodium sulfide and potassium sulfide used as the reactant were investigated. The samples were characterized by scanning electron microscopy coupling with energy-dispersive X-ray spectroscopy (FESEM-EDX), and transmission electron microscopy (TEM). The results show that the nanoparticles of zinc sulfide were obtained from sodium sulfide and potassium sulfide with particles sizes are in the range of 10 to 50 nm and 25 to 50 nm respectively. In addition, from FESEM microphotograph the primary ZnS particles size of around 5 nm and 25 nm were obtained by 10% salt (sodium chloride, potassium chloride, sodium acetate) addition with sodium sulfide and potassium sulfide reactant respectively.

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188-191

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] X. Fang, T. Zhai, U. K. Gautam, L. Li, L. Wu, Y. Bando, D. Golberg, ZnS nanostructures: From synthesis to applications, Prog. Mater. Sci. 56 (2011) 175-287.

DOI: 10.1016/j.pmatsci.2010.10.001

Google Scholar

[2] J. -m. Hwang, M. -O. Oh, I. Kim, J. -K. Lee, C. -S. Ha, Preparation and characterization of ZnS based nano-crystalline particles for polymer light-emitting diodes, Curr. Appl. Phys. 5 (2005) 31-34.

DOI: 10.1016/j.cap.2003.11.075

Google Scholar

[3] D. A. Reddy, G. Murali, N. M. Rao, R.P. Vijayalakshmi, B.K. Reddy, Synthesis and Optical Properties of Annealed Cr Doped ZnS Nanoparticles, Adv. Mat. Res. 678 (2013) 163-167.

DOI: 10.4028/www.scientific.net/amr.678.163

Google Scholar

[4] L. -X. Shao, K. -H. Chang, H. -L. Hwang, Zinc sulfide thin films deposited by RF reactive sputtering for photovoltaic applications, App. Surf. Sci. 212–213 (2003) 305-310.

DOI: 10.1016/s0169-4332(03)00085-0

Google Scholar

[5] Z. Y. Zhong, E. S. Cho, S. J. Kwon, Characterization of the ZnS thin film buffer layer for Cu(In, Ga)Se2 solar cells deposited by chemical bath deposition process with different solution concentrations, Mater. Chem. Phys. 135 (2012) 287-292.

DOI: 10.1016/j.matchemphys.2012.03.090

Google Scholar

[6] Z. Cao, L. Sun, X. Cao, Y. He, Preparation and Characterization of Helical Structure ZnS by Solvothermal Method, Adv. Mat. Res. 233 - 235 (2011) 1954-(1957).

Google Scholar

[7] X. Yan, E. Michael, S. Komarneni, J. R. Brownson, Z. -F. Yan, Microwave- and conventional-hydrothermal synthesis of CuS, SnS and ZnS: Optical properties, Ceram. Int. 39 (2013) 4757-4763.

DOI: 10.1016/j.ceramint.2012.11.062

Google Scholar

[8] M. Salavati-Niasari, F. Davar, M. Mazaheri, Synthesis and characterization of ZnS nanoclusters via hydrothermal processing from [bis(salicylidene)zinc(II)], J. Alloy. Compd. 470 (2009) 502-506.

DOI: 10.1016/j.jallcom.2008.03.048

Google Scholar

[9] P. K. Ghosh, U. N. Maiti, S. Jana, K. K. Chattopadhyay, Field emission from ZnS nanorods synthesized by radio frequency magnetron sputtering technique, Appl. Surf. Sci. 253 (2006) 1544-1550.

DOI: 10.1016/j.apsusc.2006.02.037

Google Scholar

[10] W. Chen, X. Xu, P. Dai, Y. Chen and Z. Jiang, Properties of ZnS Thin Films Prepared by CBD under Different Concentration of Complexing Agent, Adv. Mat. Res. 472 - 475 (2012) 1572-1576.

DOI: 10.4028/www.scientific.net/amr.472-475.1572

Google Scholar

[11] N. R Pawaskar, S. D Sathaye, M. M Bhadbhade, K . R Patil, Applicability of liquid–liquid interface reaction technique for the preparation of zinc sulfide nano particulate thin films, Mater. Res. Bull. 37 (2002) 1539-1546.

DOI: 10.1016/s0025-5408(02)00845-0

Google Scholar

[12] L. Qi, B. I Lee, J. M Kim, J. E Jang, J. Y Choe, Synthesis and characterization of ZnS: Cu, Al phosphor prepared by a chemical solution method, J. Lumin. 104 (2003) 261-266.

DOI: 10.1016/s0022-2313(03)00079-6

Google Scholar

[13] K. P. Kalyanikutty, U. K. Gautam, C. N. R. Rao, Ultra-thin crystalline films of ZnS and PbS formed at the organic–aqueous interface, Solid. State. Sci. 8 (2006) 296-302.

DOI: 10.1016/j.solidstatesciences.2006.02.005

Google Scholar