Optical Absorption and Photoluminescence Properties of Dy3+ Ions in Bi2O3-SiO2-B2O3 Glass System

Narong Sangwaranatee; Yaowaluk Tariwong; Sunisa Sarachai; Jakrapong Kaewkhao; Natthakridta Chanthima

doi:10.4028/www.scientific.net/AMR.979.280

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 979Optical Absorption and Photoluminescence...

Optical Absorption and Photoluminescence Properties of Dy³⁺ Ions in Bi₂O₃-SiO₂-B₂O₃ Glass System

Abstract:

This research studied the effect of dysprosium on the physical, optical and luminescence properties of the bismuth borosilicate glass in compositions 40Bi₂O₃ : 20SiO₂ : (40-x)B₂O₃ : xDy₂O₃ (where x = 0.0, 0.5, 1.0, 1.5, 2.0 and 2.5 mol%). The glass systems have been prepared at 1100 °C by melt quenching technique. The results showed that the density and molar volume of glass samples are between 4.6477 ± 0.0020 to 5.0047 ± 0.0041 g/cm³ and 45.6608 to 48.6797 cm³/mol, respectively. The values of density and molar volume of these glasses were not depend on the Dy₂O₃ concentration. The optical absorption spectra of glass samples in the UV-Vis-NIR region shows absorption bands at 794, 906, 1094, 1276 and 1690 nm, respectively. The photoluminescence spectra show emission bands at 482 (blue), 576 (green), 663 (yellow) and 756 (red) nm under 453 nm excitation wavelength. The emission spectrum at 576 nm has shown a strongest intensity.

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Advanced Materials Research (Volume 979)

Pages:

280-284

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.979.280

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Online since:

June 2014

Authors:

Narong Sangwaranatee, Yaowaluk Tariwong, Sunisa Sarachai, Jakrapong Kaewkhao, Natthakridta Chanthima*

Keywords:

Dysprosium, Glass, Optical Property, Photoluminescence (PL)

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