Synthesis, Crystal Structures and Properties of Two Transition Metal Complexes Based on 4, 4'-{[2, 2'-(ethane-1, 2-bicarboxymethyl)] amino-bis(acetyl)} Dibenzoic Acid

Abstract:

Two isostructural transition metal complexes based on the 4,4'-{[2,2'-(ethane-1,2-bicarboxymethyl)] amino-bis (acetyl)} dibenzoic acid (H₄L) were synthesized under hydrothermal conditions, namely, [M(H₂L)(H₂O)]·3H₂O (M=Ni, 1 ; Co, 2). The two compounds were structurally characterized by infrared spectra, thermogravimetric analysis and single crystal X-ray diffractions. Compounds 1-2 are mononuclear units and further extended to generate the two dimensional structures by hydrogen-bonds and π-π interactions. Compounds 1 exhibit the high thermal stability.

• Periodical: Advanced Materials Research (Volume 997)
• Pages: 255-259
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.997.255
• Online since: August 2014
• Authors: Ying Ying Bing, Hong Gao, Ming Hu*
• Keywords: Coordination Compound, Crystal Structure, Hydrothermal Synthesis, Transition Metal

References

[1] L.Q. Ma, D.J. Mihalcik, W.B. Lin, Highly Porous and Robust 4, 8-Connected Metal-Organic Frameworks for Hydrogen Storage, J Am Chem Soc. 131 (2009) 4610-4612.

DOI: 10.1021/ja809590n

[2] Z.L. Liao, G.D. Li, M.H. Bi, J.S. Chen, Preparation, structures, and photocatalytic properties of three new uranyl-organic assembly compounds, Inorg Chem. 47 (2008) 4844-4853.

DOI: 10.1021/ic800109y

[3] K.K. Bisht, E. Suresh, Co(II)/Zn(II) Coordination Polymers with Angular Dicarboxylate and Flexible N-Donor Struts: Structural and Photoluminescence Studies, Cryst. Growt Des. 13 (2013) 664-670.

DOI: 10.1021/cg301329c

[4] X.M. Zhang, Y.Q. Wang, K. Wang, E.Q. Gao, C.M. Liu, Metamagnetism and slow magnetic dynamics in an antiferromagnet composed of cobalt(II) chains with mixed azide-carboxylate bridges, Chem Commun. 47 (2011) 1815-1817.

DOI: 10.1039/c0cc04492j

[5] T. R. Cook, Y.R. Zheng,  P. J. Stang, Metal-Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal-Organic Materials, Chem. Rev. 113 (2013) 734-777.

DOI: 10.1021/cr3002824

[6] S. Hazra, B. Sarkar, S. Naiya, M.G. B. Drew, A. Frontera, D. Escudero, A. Ghosh, Self-Assembled Molecular Complexes and Coordination Polymers of Cd-II, Hexamine, and Monocarboxylates: Structural Analysis and Theoretical Studies of Supramolecular Interactions, Cryst Growth Des. 10 (2010).

DOI: 10.1021/cg901245z

[7] B. Xu, X. Li, Z. He, Z. Lin, R. Cao, Interpenetrated metal-organic frameworks of self-catenated four-connected mok nets, Chem. Commun. 47 (2011) 3766-3768.

DOI: 10.1039/c1cc10411j

[8] A.L. Cheng, Y. Ma, J.Y. Zhang, E.Q. Gao, Towards tuning the packing and entanglement of zigzag coordination chains by terminal ligands, Dalton Trans. (2008) 1993-(2004).

DOI: 10.1039/b715949h

[9] T. H. Madden, A. K. Datye, M. Fulton, M. R. Prairie, S. A. Majumdar, B.M. Stange, Oxidation of metal - EDTA complexes by TiO2 photocatalysis, Environ. Sci. Technol. 31 (1997) 3475-3481.

DOI: 10.1021/es970226a

[10] L.S. Wei, F.L. Zhong, Synthesis and evaluation of Gd-DTPA-labeled arabinogalactans as potential MRI contrast agents, Carbohydrate Research. 343 (2008) 685-688.

DOI: 10.1016/j.carres.2008.01.008

[11] Y. W. Ebright, Y. Chen, Ludescher, D. Richard, N-(Iodoacetyl)-p-phenylenediamine-EDTA: A reagent for high-efficiency incorporation of an EDTA-metal complex at a rationally selected site within a protein, Bioconjugate Chemistry. 4 (1993) 219-225.

DOI: 10.1021/bc00021a006

[12] L.M. Chen Z.F. Hao, X. M. Wang, synthesis of Ethylenediamine tetraacetic acid derivatives containing aromatic amides, Chinese Journal of Synthetic Chemistry. 1 (2010) 71-73.

[13] Sheldrick GM(1997) SHELXS-97, Program for the Crystal Structure Refinement, University of Göttingen, Germany.

[14] X. Li, B.L. Wu, R.Y. Wang, H.Y. Zhang, C.Y. Niu, Y.Y. Niu, H.W. Hou, Hierarchical Assembly of Extended Coordination Networks Constructed by Novel Metallacalix.

DOI: 10.1021/ic901113p

[4] arenes Building Blocks, Inorganic Chemistry. 49 (2010) 2600-2613.