Investigation of the Optimal Heat Treatment of As-Cast Al-5.7Si-2Cu-0.3Mg Aluminium Alloys

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The aim of this work is to investigate the optimum heat treatment for Al-5.7Si-2Cu-0.3Mg aluminium alloys and study its effect on microstructure, phase transformations, and hardness. The test specimens were taken from the as-received alloy. Solution treatment was performed at 485°C and 500°C under various solution treatment times for 4, 8, 10, and 12h, and the samples were then hot water quenched at 60°C, followed by aged hardening at 150°C, 170°C and 190°C for 2,6,10, and 14h, and subsequently air-cooled. The hardness of the Al-5.7%Si-2Cu%-0.3%Mg alloys were determined using a Rockwell hardness tester. Scanning electron microscopy (SEM) and optical microscopy (OM) were used to determine the microstructure of the samples, while X-ray diffraction (XRD) was used to identify the phase compositions. The resulting microstructures and hardness values were compared to the corresponding as-cast samples. It can be seen that the solution treatment at 485°C for 12 h and aging at 190°C for 10 h are the optimum T6 heat treatment conditions that would result in hardening precipitates over the as-cast alloy. OM and SEM morphologies show significant microstructure evaluation of improved distribution of the Si particles. After T6 treatment, the morphology of Si particles in the as-cast Al-5.7Si-2Cu-0.3Mg alloy changes from long and coarse plate-like grains to fine spherical shaped grain. The XRD plots confirmed the relatively high concentration of Al, Si, and Al2Cu in the heat treated Al-5.7%Si-2Cu%-0.3%Mg alloy relative to that of the as-cast alloy. The hardness of the T6 alloy also increased.

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April 2021

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[1] T.A. Costa, M. Dias, L.G. Gomes, O.L. Rocha, and A. Garcia, Effect of solution time in T6 heat treatment on microstructure and hardness of a directionally solidified Al-Si-Cu alloy,, Journal of Alloys and Compounds, vol. 683, p.485–494, (2016).

DOI: 10.1016/j.jallcom.2016.05.099

Google Scholar

[2] K.S. Alhawari, M.Z. Omar, M.J. Ghazali, M.S. Salleh, and M.N. Mohammed, Dry sliding wear behaviour of thixoformed hypoeutectic Al-Si-Cu alloy with different amounts of magnesium,, Composite Interfaces, vol. 23, no. 6, p.519–531, (2016).

DOI: 10.1080/09276440.2016.1164496

Google Scholar

[3] K.N. Campo, C.T.W. Proni, and E.J. Zoqui, Influence of the processing route on the microstructure of aluminum alloy A356 for thixoforming,, Materials Characterization, vol. 85, p.26–37, (2013).

DOI: 10.1016/j.matchar.2013.08.011

Google Scholar

[4] M. Zhu, Z. Jian, G. Yang, and Y. Zhou, Effects of T6 heat treatment on the microstructure, tensile properties, and fracture behavior of the modified A356 alloys,, Materials and Design, vol. 36, p.243–249, (2012).

DOI: 10.1016/j.matdes.2011.11.018

Google Scholar

[5] P. Cavaliere, E. Cerri, and P. Leo, Effect of heat treatments on mechanical properties and damage evolution of thixoformed aluminium alloys,, Materials Characterization, vol. 55, no. 1, p.35–42, (2005).

DOI: 10.1016/j.matchar.2005.02.006

Google Scholar

[6] E. Sjolander and S. Seifeddine, The heat treatment of Al-Si-Cu-Mg casting alloys,, Journal of Materials Processing Technology, vol. 210, no. 10, p.1249–1259, (2010).

DOI: 10.1016/j.jmatprotec.2010.03.020

Google Scholar

[7] M. Javidani and D. Larouche, Application of cast Al–Si alloys in internal combustion engine components,, International Materials Reviews, vol. 59, no. 3, p.132–158, (2014).

DOI: 10.1179/1743280413y.0000000027

Google Scholar

[8] S.W. Choi et al., The effects of cooling rate and heat treatment on mechanical and thermal characteristics of Al-Si-Cu-Mg foundry alloys,, Journal of Alloys and Compounds, vol. 617, p.654–659, (2014).

DOI: 10.1016/j.jallcom.2014.08.033

Google Scholar

[9] A. Ardell, Precipitation hardening,, Modern Physical Metallurgy, vol. 16, no. 12, p.2131--2165, (1985).

Google Scholar

[10] E. Rincon, H.F. Lopez, M.M. Cisneros, and H. Mancha, Temperature effects on the tensile properties of cast and heat treated aluminum alloy A319,, Materials Science and Engineering: A, vol. 519, no. 1, p.128–140, (2009).

DOI: 10.1016/j.msea.2009.05.022

Google Scholar

[11] M. Tash, F.H. Samuel, F. Mucciardi, H.W. Doty, and S. Valtierra, Experimental correlation between metallurgical parameters and hardness in heat-treated 319 alloys : A quantitative study using factorial analysis,, Transactions of the American Foundry Society, vol. 114, no. 2, p.71–84, (2006).

DOI: 10.1016/j.msea.2006.06.129

Google Scholar

[12] S. Menargues, E. Martín, M.T. Baile, and J.A. Picas, New short T6 heat treatments for aluminium silicon alloys obtained by semisolid forming,, Materials Science and Engineering: A, vol. 621, p.236–242, (2015).

DOI: 10.1016/j.msea.2014.10.078

Google Scholar

[13] M. Polmear, Ian and StJohn, David and Nie, Jian-Feng and Qian, Light alloys: metallurgy of the light metals, vol. 37. Elsevier, (2017).

DOI: 10.1016/b978-0-08-099431-4.00001-4

Google Scholar

[14] F. Czerwinski, Thermochemical treatment of metals,, in Heat Treatment Conventional and novel applications, InTech, 2012, p.247–286.

DOI: 10.5772/51566

Google Scholar

[15] R. Sharma, Anesh, and D.K. Dwivedi, Solutionizing temperature and abrasive wear behaviour of cast Al–Si–Mg alloys,, Materials & Design, vol. 28, no. 6, p.1975–1981, (2007).

DOI: 10.1016/j.matdes.2006.04.011

Google Scholar

[16] M. Zeren, The effect of heat-treatment on aluminum-based piston alloys,, Materials & Design, vol. 28, p.2511–2517, (2007).

DOI: 10.1016/j.matdes.2006.09.010

Google Scholar

[17] F.H. Samuel, Incipient melting of Al5-Mg8-Si6-Cu2 and Al2Cu intermetallics in unmodified and strontium-modified Al–Si–Cu–Mg (319) alloys during solution heat treatment,, Journal of Materials Science, vol. 33, p.2283–2297, (1998).

DOI: 10.1023/a:1004383203476

Google Scholar

[18] Z. Li, A.M. Samuel, F.H. Samuel, C. Ravindran, and S. Valtierra, Effect of alloying elements on the segregation and dissolution of CuAl2 phase in Al-Si-Cu 319 alloys,, Journal of Materials Science, vol. 38, no. 6, p.1203–1218, (2003).

DOI: 10.1023/a:1022857703995

Google Scholar

[19] B. Dang, C.C. Liu, F. Liu, Y.Z. Liu, and Y.B. Li, Effect of as-solidified microstructure on subsequent solution-treatment process for A356 Al alloy,, Transactions of Nonferrous Metals Society of China, vol. 26, no. 3, p.634–642, (2016).

DOI: 10.1016/s1003-6326(16)64152-3

Google Scholar

[20] T. Il So, H.C. Jung, C. Do Lee, and K.S. Shin, Effects of T6-treatment on the defect susceptibility of tensile strength to microporosity variation in low pressure die-cast A356 alloy,, Metals and Materials International, vol. 21, no. 5, p.842–849, (2015).

DOI: 10.1007/s12540-015-5247-3

Google Scholar

[21] A.M. Gokhale and G.R. Patel, Quantitative fractographic analysis of variability in tensile ductility of a squeeze cast Al-Si-Mg base alloy,, Materials Characterization, vol. 54, no. 1, p.13–20, (2005).

DOI: 10.1016/j.matchar.2004.10.003

Google Scholar

[22] J. Peng, X. Tang, J. He, and D. Xu, Effect of heat treatment on microstructure and tensile properties of A356 alloys,, Transactions of Nonferrous Metals Society of China, vol. 21, no. 9, p.1950–1956, (2011).

DOI: 10.1016/s1003-6326(11)60955-2

Google Scholar

[23] L. Kyuhong, Y.N. Kwon, and S. Lee, Effects of eutectic silicon particles on tensile properties and fracture toughness of A356 aluminum alloys fabricated by low-pressure-casting, casting-forging, and squeeze-casting processes,, Journal of Alloys and Compounds, vol. 461, no. 1–2, p.532–541, (2008).

DOI: 10.1016/j.jallcom.2007.07.038

Google Scholar

[24] F. Vatansever, A.T. Ertürk, and S. Karabay, Improving mechanical properties of AlSi10Mg aluminum alloy using ultrasonic melt treatment combined with T6 heat treatment,, Kovove Materialy, vol. 57, no. 1, p.33–43, (2019).

DOI: 10.4149/km_2019_1_33

Google Scholar

[25] L. Lasa and J.M. Rodriguez-Ibabe, Effect of composition and processing route on the wear behaviour of Al-Si alloys,, Scripta Materialia, vol. 46, no. 6, p.477–481, (2002).

DOI: 10.1016/s1359-6462(02)00020-9

Google Scholar

[26] D.K. Dwivedi, T.S. Arjun, P. Thakur, H. Vaidya, and K. Singh, Sliding wear and friction behaviour of Al-18% Si-0.5% Mg alloy,, Journal of Materials Processing Technology, vol. 152, no. 3, p.323–328, (2004).

DOI: 10.1016/j.jmatprotec.2004.04.379

Google Scholar

[27] D. Dighe and A.M. Gokhale, Relationship between microstructural extremum and fracture path in a cast Al-Si-Mg alloy,, Scripta Materialia, vol. 37, no. 9, p.1435–1440, (1997).

DOI: 10.1016/s1359-6462(97)00277-7

Google Scholar

[28] S. Alkahtani, Mechanical performance of heat treated 319 alloys as a function of alloying and aging parameters,, Materials and Design, vol. 41, p.358–369, (2012).

DOI: 10.1016/j.matdes.2012.04.034

Google Scholar

[29] M. Tash, F.H. Samuel, F. Mucciardi, and H.W. Doty, Effect of metallurgical parameters on the hardness and microstructural characterization of as-cast and heat-treated 356 and 319 aluminum alloys,, Materials Science and Engineering: A, vol. 443, no. 1–2, p.185–201, (2007).

DOI: 10.1016/j.msea.2006.08.054

Google Scholar

[30] E. Feyzullahoglu, A.T. Erturk, and E.A. Guven, Influence of forging and heat treatment on wear properties of Al-Si And Al-Pb bearing alloys in oil lubricated conditions,, Transactions of Nonferrous Metals Society of China, vol. 23, no. 12, p.3575–3583, (2013).

DOI: 10.1016/s1003-6326(13)62903-9

Google Scholar

[31] C.F. Ferrarini, C. Bolfarini, C.S. Kiminami, and W.J.F. Botta, Microstructure and mechanical properties of spray deposited hypoeutectic Al – Si alloy,, Materials Science and Engineering: A, vol. 375, p.577–580, (2004).

DOI: 10.1016/j.msea.2003.10.062

Google Scholar

[32] M.S. Salleh, M.Z. Omar, J. Syarif, K.S. Alhawari, and M.N. Mohammed, Microstructure and mechanical properties of thixoformed A319 aluminium alloy,, Materials and Design, vol. 64, p.142–152, (2014).

DOI: 10.1016/j.matdes.2014.07.014

Google Scholar

[33] Y. Birol, Thixoforming of en AW-2014 alloy at high solid fraction,, Journal of Materials Processing Technology, vol. 211, no. 11, p.1749–1756, (2011).

DOI: 10.1016/j.jmatprotec.2011.05.016

Google Scholar

[34] T. Yasmin, A.A. Khalid, and M.M. Haque, Tribological (wear) properties of aluminum-silicon eutectic base alloy under dry sliding condition,, Journal of Materials Processing Technology, vol. 153–154, no. 1–3, p.833–838, (2004).

DOI: 10.1016/j.jmatprotec.2004.04.147

Google Scholar

[35] I. Aguilera Luna, H. Mancha Molinar, M.J. Castro Román, J.C. Escobedo Bocardo, and M. Herrera Trejo, Improvement of the tensile properties of an Al-Si-Cu-Mg aluminum industrial alloy by using multi stage solution heat treatments,, Materials Science and Engineering A, vol. 561, p.1–6, (2013).

DOI: 10.1016/j.msea.2012.10.064

Google Scholar

[36] G.S. Mousavi, M. Emamy, and J. Rassizadehghani, The effect of mischmetal and heat treatment on the microstructure and tensile properties of A357 Al-Si casting alloy,, Materials Science and Engineering A, vol. 556, p.573–581, (2012).

DOI: 10.1016/j.msea.2012.07.029

Google Scholar