The Effect of Sn-Doped Li7La3Zr2O12 on the Structure and Electrical Properties of Electrolyte Material for Li-Ion Batteries

Siti Nur Adlina Norazman; Mohd Sobri Idris; Rozana Aina Maulat Osman; Mogalahalli Venkatesh Reddy; Ku Noor Dhaniah Ku Muhsen; Nor Zachy Fernandez

doi:10.4028/p-y265n3

Paper Titles

Study on Electrical Properties and Morphology of Garnet-Type Structure Li₇La₃Ce₂O₁₂with Different Synthesizing Routes
p.9

Structural Analysis of Li₇La₃ZrSnO₁₂ as a Solid Electrolyte for all Solid-State Batteries
p.15

Structural Analysis and Electrical Properties of Li₇La₃Ce₂O₁₂ as a Solid Electrolyte for all Solid-State Lithium-Ion Batteries
p.21

The Structure and Electrical Properties of Li₇La₃Zr_1.0Sn_1.0O₁₂as Electrolyte Material for Li-ion Batteries
p.27

The Effect of Sn-Doped Li₇La₃Zr₂O₁₂on the Structure and Electrical Properties of Electrolyte Material for Li-Ion Batteries
p.33

Structural, Microstructural and Dielectric Properties of BaTi_0.905Sn_0.095O₃ Ceramic
p.41

Structural Analysis and Dielectric Properties of Oxygen Non-Stoichiometry 5% Fe-Doped BaTiO₃ Ceramic
p.47

Enhanced Dielectric Properties of Ba_0.85Sr_0.15TiO₃ Ceramic by 8% Zirconium Doping
p.53

The Structural and Dielectric Properties of BaTi_0.88Zr_0.12O₃ Ceramic
p.59

HomeAdvances in Science and TechnologyAdvances in Science and Technology Vol. 118The Effect of Sn-Doped Li7La3Zr2O12 on the...

The Effect of Sn-Doped Li₇La₃Zr₂O₁₂on the Structure and Electrical Properties of Electrolyte Material for Li-Ion Batteries

Abstract:

High purity of Li₇La₃Zr_2-xSn_xO₁₂ (x = 0.00, 0.50, 1.00, 1.50 and 1.00) samples that formed garnet-type crystal structure were prepared using biopolymer sol-gel method. The structure phase of Li₇La₃Zr_2-xSn_xO₁₂ (x = 0.00, 0.50, 1.00, 1.50 and 1.00) powder was indexed with the parent composition of Li₇La₃Zr₂O₁₂structure with space group of Ia-3d for cubic phase. Impedance spectroscopy analysis was used to determine the conductivity of Li₇La₃Zr_2-xSn_xO₁₂ (x = 0.00, 0.50, 1.00, 1.50 and 1.00) samples. The samples exhibit the conductivity about 10^-6to 10^-4 Scm^-1 .The SEM micrographs reveal that the grain of the samples exhibits well developed particles of irregular shape.

You might also be interested in these eBooks

Advancement of Materials, Manufacturing and Devices (ICAMaDe)

View Preview

Advancement of Materials, Manufacturing and Devices

View Preview

Info:

Periodical:

Advances in Science and Technology (Volume 118)

Pages:

33-38

DOI:

https://doi.org/10.4028/p-y265n3

Citation:

Cite this paper

Online since:

September 2022

Authors:

Siti Nur Adlina Norazman, Mohd Sobri Idris*, Rozana Aina Maulat Osman, Mogalahalli Venkatesh Reddy, Ku Noor Dhaniah Ku Muhsen, Nor Zachy Fernandez

Keywords:

Electrolyte Materials, Impedance Spectroscopy, Lithium-Ion Batteries, X-Ray Diffraction

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] M. Armand and J. M. Tarascon, Nature, 451, 652657 (2008).

Google Scholar

[2] Y. Inaguma, C. Liquan, M. Itoh, T. Nakamura, T. Uchida, H. Ikuta and M. Wakihara, Solid State Commun., 86, 689693 (1993).

DOI: 10.1016/0038-1098(93)90841-a

Google Scholar

[3] R. Murugan, V. Thangadurai and W. Weppner, Angew. Chem., 119, 79257928 (2007).

Google Scholar

[4] A. Logéat, T. Köhler, U. Eisele, B. Stiaszny, A. Harzer, M. Tovar, A. Senyshyn, H. Ehrenberg and B. Kozinsky, Solid State Ionics, 206, 3338 (2012).

DOI: 10.1016/j.ssi.2011.10.023

Google Scholar

[5] A. Gupta, R. Murugan, M. P. Paranthaman, Z. Bi, C. A. Bridges, M. Nakanishi, A. P. Sokolov, K. S. Han, E. W. Hagaman, H. Xie, C. B. Mullins and J. B. Goodenough, J. Power Sources, 209, 184188 (2012).

DOI: 10.1016/j.jpowsour.2012.02.099

Google Scholar

[6] Hui Xie , Yutao Li , J. B. Goodenough, Low-temperature synthesis of Li7La3Zr2O12 with cubic garnet-type structure. Materials Research Bulletin (2012).

DOI: 10.1016/j.materresbull.2012.01.027

Google Scholar

[7] Mohd Sobri Idris and Rozana A.M. Osman, Structure Refinement Strategy of Li-based Complex Oxides Using GSAS-EXPGUI Software Package. Advanced Materials Research, Vol 795 (2013) pp.479-482.

DOI: 10.4028/www.scientific.net/amr.795.479

Google Scholar

[8] Ku Noor Dhaniah Ku Muhsen, Rozana Aina Maulat Osman, Mohd Sobri Idris, Structure refinement and impedance analysis of Ba0.85Ca0.15Zr0.10Ti0.90O3 ceramics sintered in air and nitrogen. Journal of Materials Science: Materials in Electronics (2019).

DOI: 10.1007/s10854-019-02433-3

Google Scholar