Influence of Ferrochrome Slag Co-Binder on Mechanical Behaviour of Fly Ash Geopolymer Mortars

Article Preview

Abstract:

An experimental study was conducted to investigate the mechanical properties of fly ash geopolymer binder system containing 0% to 30% ferrochrome slag. Paste and mortar samples were prepared using a mixture of sodium silicate (SS) and sodium hydroxide (SH), as the alkali – activator solution made at varied SS/SH ratio of 1.5 to 2.3, along with varied sodium hydroxide concentration ranging from 10.7 to 15.2 M. The ratio of alkali – activator to raw aluminosilicate material, was kept constant at 0.50, 0.52 or 0.54. Paste or mortar cubes of 50 mm size were cast and cured at 23, 40, 60 or 80 °C for compressive strength testing, while prisms of 25 × 25 × 285 mm size were prepared for drying shrinkage monitoring. Also measured were workability, density, water absorption and pore volume. Microanalytical studies were done using scanning electron microscopy, X – ray diffraction analysis, and Fourier transform infrared spectroscopy. It was found that fly ash geopolymer mortars containing 10% ferrochrome slag and cured at normal temperature gave the optimal compressive strength. There was significant increase in drying shrinkage of mortars, as the content of ferrochrome slag increased, but overall values were within normal range. Keywords: Fly ash geopolymer, Compressive strength, Ferrochrome slag, Drying shrinkage.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

3-17

Citation:

Online since:

March 2024

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Karakoç M. B., Türkmen I., Maras M.M., Kantarci F., Demirbog R., M. and Toprak U., 2014. Mechanical properties and setting time of ferrochrome slag based geopolymer paste and mortar. Construction and Building Materials, Volume 72, pp.283-292.

DOI: 10.1016/j.conbuildmat.2014.09.021

Google Scholar

[2] Shekhovtsova, J., 2015. Using South African fly ash as a component of Alkali-activated binder, Pretoria: University of Pretoria

Google Scholar

[3] Tchadjie, L. and Ekolu, S. O., 2018. Enhancing the reactivity of aluminosilicate materials toward geopolymer synthesis. Journal of materials science, 53(7):4709-4733.

DOI: 10.1007/s10853-017-1907-7

Google Scholar

[4] Arbi, K., 2016. A review on the durability of alkali-activated fly ash/slag systems: advances, issues, and perspectives. Industrial & Engineering Chemistry Research, pp.5439-5435.

DOI: 10.1021/acs.iecr.6b00559

Google Scholar

[5] Pather B., Ekolu S.O. and Quainoo H., 2021. Effects of aggregate types on acid corrosion attack upon fly – ash geopolymer and Portland cement concretes – comparative study, Construction and Building Materials 313, 125468.

DOI: 10.1016/j.conbuildmat.2021.125468

Google Scholar

[6] Nkohla, M. A., 2006. Characterization of ferrochrome smelter slag and its implications in metal accounting, Cape Town: Cape Peninsula University of Technology.

Google Scholar

[7] Nath, S. K., 2018. Geopolymerization behaviour of ferrochrome slag and fly ash blends. Construction and Building Materials , pp.487-494.

DOI: 10.1016/j.conbuildmat.2018.06.070

Google Scholar

[8] Kumar P. H., Srivastava A., Kumar V. and Singh V. K., 2014. Implementation properties of industrial waste ferrochrome slag in conventional and low cement castables: Effect of calcined alumina. Journal of Asian Cemaric Societies, Volume 2, pp.371-379.

DOI: 10.1016/j.jascer.2014.08.001

Google Scholar

[9] Falayi, T., 2019. Sustainable solidification of ferrochrome slag through geopolymerisation: a look at the effect of curing time, type of activator and liquid solid ratio. Sustainable Environment Research, Volume 29, p.21.

DOI: 10.1186/s42834-019-0022-7

Google Scholar

[10] Lind B. B., FaÈllman A. M., and Larsson L. B., 2001. Environmental impact of ferrochrome slag in road construction. Waste Management Volume 21, pp.255-264.

DOI: 10.1016/s0956-053x(00)00098-2

Google Scholar

[11] Perera D. S., Uchida O., Vance E. R., and Finnie K. S., 2007. Influence of curing schedule on the integrity of Geopolymers. Journal of materials science, pp.3099-3106.

DOI: 10.1007/s10853-006-0533-6

Google Scholar

[12] Rovnanik, P., 2010. Effect of curing temperature on the development of hard structure of Metakaolin-based geopolymer concrete. Construction and Building Materials, pp.1176-1183.

DOI: 10.1016/j.conbuildmat.2009.12.023

Google Scholar

[13] Nagral, M. R., 2014. Effect of curing temperature and curing hours on the properties of geopolymer concrete. International Journal of Computational Engineering Research, pp.2250-3005.

Google Scholar

[14] Singh, N. B., 2017. Foamed geopolymer concrete. Science Direct, pp.15243-15252.

Google Scholar

[15] Nanavati S., 2017. A review on fly ash based geopolymer concrete. Journal of Mechanical and Civil Engineering, 14(4), pp.12-16.

Google Scholar

[16] Arioz E., Arioz O. and Kockar O. M., 2020. Geopolymer synthesis with low sodium hydroxide concentration. Iranian Journal of Science and Technology: Transactions of Civil Engineering Volume 44 (Suppl 1), p.525–S533

DOI: 10.1007/s40996-019-00336-1

Google Scholar

[17] Davidovits, J., 2005. Geopolymer chemistry and sustainable development. The poly(sialate) terminology: a very useful and simple model for the promotion and understanding of green-chemistry. Geopolymer Institute, pp.9-12.

Google Scholar

[18] Nurrudin M. F., Kusbiantoro A. K., Qazi S. Q., Darmawan M. D., and Husin N. H. , 2011. Development of gepolymer concrete with different curing conditions. IPTEK: The Journal for Technology and Science, 22(1), pp.24-28.

DOI: 10.12962/j20882033.v22i1.54

Google Scholar

[19] Deb, P. S., 2013. Strength and permeation properties of slag blended fly ash based geopolymer concrete. Advanced Materials Research, Volume 651, pp.168-173.

DOI: 10.4028/www.scientific.net/amr.651.168

Google Scholar

[20] Naghizadeh, A. and Ekolu, S.O., 2022. Activator-related effects of sodium hydroxide storage solution in standard testing of fly ash geopolymer mortars for alkali–silica reaction. Materials and Structures, 55(1), p.22.

DOI: 10.1617/s11527-021-01875-8

Google Scholar

[21] Hardjito, D.,Wallah S.E., Sumajouw, D.M.J. and Rangan B.V., 2004. On the development of fly ash-based geopolymer concrete, ACI Materials Journal, 101, 467-472.

DOI: 10.1007/s10853-006-0523-8

Google Scholar

[22] Naghizadeh A., and Ekolu S. O., 2018. Effect of mix parameters on strength of geopolymer mortars - experimental study, 6th International Conference on the Durability of Concrete Structures, 18 - 20 July, Leeds, United Kingdom, 315-319.

Google Scholar

[23] Naghizadeh A., and Ekolu S. O., 2020. Effects of compositional and physico - chemical mix design parameters on properties of fly ash geopolymer mortars. Silicon, 13 (12) 4669-4680.

DOI: 10.1007/s12633-020-00799-2

Google Scholar

[24] Özcan A., and Karakoç M. B., 2019. The resistance of blast furnace slag- and ferrochrome slag-based geopolymer concrete against acid Attack. International Journal of Civil Engineering, Volume 17, pp.1571-1583.

DOI: 10.1007/s40999-019-00425-2

Google Scholar

[25] Jena S., and Panigrahi R, 2019. Performance assessment of geopolymer concrete with partial replacement of ferrochrome slag as coarse aggregate. International Communications in Heat and Mass Transfer , pp.242-248.

DOI: 10.1016/j.conbuildmat.2019.06.045

Google Scholar

[26] ASTM C 230/C230M - 21: Standard specification for flow table for use in tests of hydraulic cement, 2021. Compass ASTM. [Online]. Available at: https://0-compass-astm-org.ujlink.uj.ac.za/download/C230C230M.6952.pdf

Google Scholar

[27] ASTM C109/C109M - 20b: Standard testing method for compressive strength of hydraulic cement mortars using 2-in. or [50 mm] cube specimens, 2020. Compass ASTM. [Online] Available at: https://0-compass-astm-org.ujlink.uj.ac.za/EDIT/html_annot.cgi?C109+20b

DOI: 10.1520/c0109_c0109m-20

Google Scholar

[28] ASTM C157/C157M -17: Standard for testing method for length change of hardened hydraulic-cement mortar and concrete, 2014. Compass ASTM. [Online] Available at: https://0-compass-astm-org.ujlink.uj.ac.za/EDIT/html_annot.cgi?C157+17

Google Scholar

[29] ASTM C642-13: Standard for testing method for density, absorption, and voids in hardened concrete, 2013. Compass ASTM. [Online]. Available at: https://0-compass-astm-org.ujlink.uj.ac.za/EDIT/html_annot.cgi?C642+13

Google Scholar

[30] Ekolu, S. O., 2014. Potential South African standard sand for cement mortar testing research. Johannesburg, Proceedings of the First International Conference on Construction Materials and Structures, pp.253-260.

Google Scholar

[31] Naghizadeh, A. and Ekolu S.O., 2019. A comprehensive mix design method of fly ash geopolymer mortars, Construction and Building Materials, 202, 704-717. ISSN: ISSN: 0950-0618

DOI: 10.1016/j.conbuildmat.2018.12.185

Google Scholar

[32] Naghizadeh, A., Ekolu, S. O., Tchadjie, L. N., and Solomon, F. 2023. Long-term strength development and durability index quality of ambient-cured fly ash geopolymer concretes. Construction and Building Materials, 374, 130899.

DOI: 10.1016/j.conbuildmat.2023.130899

Google Scholar

[33] Naghizadeh A. 2019, Mix design and alkali resistance of fly ash geopolymer binders, PhD Thesis, Department of Civil Engineering Science, University of Johannesburg, 316p.

Google Scholar

[34] Pather B. 2022, Acid resistant portland cement and geopolymer concretes, MEng Dissertation, Department of Civil Engineering Science, University of Johannesburg, 173p.

Google Scholar

[35] Frasson B. J. and Rocha J. C., 2023. Reaction mechanism and mechanical properties of geopolymer based on kaolinitic coal tailings, Applied Clay Science, 106826.

DOI: 10.1016/j.clay.2023.106826

Google Scholar

[36] Pilehvar S., Sanfelix S. G., Szczotok A. M., Rodríguez J. F. et al. 2020. Effect of temperature on geopolymer and Portland cement composites modified with micro-encapsulated phase change materials, Construction and Building Materials 252, 119055.

DOI: 10.1016/j.conbuildmat.2020.119055

Google Scholar

[37] Mo, B. H., Zhu, H., Cui, X. M., He, Y., and Gong, S. Y. (2014). Effect of curing temperature on geopolymerization of metakaolin-based geopolymers. Applied clay science, 99, 144-148.

DOI: 10.1016/j.clay.2014.06.024

Google Scholar

[38] Abdalqader, A. F., Jin, F., and Al-Tabbaa, A. (2015). Characterisation of reactive magnesia and sodium carbonate-activated fly ash/slag paste blends. Construction and Building Materials, 93, 506-513.

DOI: 10.1016/j.conbuildmat.2015.06.015

Google Scholar

[39] Mishra, J., Das, S. K., Krishna, R. S., Nanda, B., Patro, S. K., & Mustakim, S. M. (2020). Synthesis and characterization of a new class of geopolymer binder utilizing ferrochrome ash (FCA) for sustainable industrial waste management. Materials today: proceedings, 33, 5001-5006.

DOI: 10.1016/j.matpr.2020.02.832

Google Scholar

[40] Revathi T., and Jeyalakshmi R., 2020. Fly ash-GGBS geopolymer in boron environment: A study on rheology and microstructure by ATR FT-IR and MAS NMR. Construction and Building Materials, 267(120965), pp.1-12.

DOI: 10.1016/j.conbuildmat.2020.120965

Google Scholar

[41] Mishra, J., Nanda, B., Patro, S. K., Das, S. K., & Mustakim, S. M. (2022). Influence of ferrochrome ash on mechanical and microstructure properties of ambient cured fly ash-based geopolymer concrete. Journal of Material Cycles and Waste Management, 24(3), 1095-1108.

DOI: 10.1007/s10163-022-01381-1

Google Scholar

[42] Nath P. K. and Kumar S., 2019. Influence of granulated silico-manganese slag on compressive strength and microstructure of ambient cured alkali-activated fly ash binder. Waste and Biomass Valorization, Volume 10, pp.2045-2055.

DOI: 10.1007/s12649-018-0213-1

Google Scholar