Paper Titles
Hybrid Triboelectric-Electrostatic Droplet Energy Harvester with Nanocomposite Interface for Wireless Power Transfer
p.27
Liquid-Metal-Assisted Piezo-Triboelectric Nanogenerator for High-Efficiency Energy Harvesting
p.33
Application of PVP/SbSI Nanocomposite for Energy Generation and Dynamic Pressure Sensing
p.39
Influence of Dimethyl Carbonate on Graphite Surface Film Formation Revealed by Potential-Resolved in situ Atomic Force Microscopy
p.47
Role of Ceramic Nanofillers in Enhancing Pore Formation and Conductivity of Solid Polymer Electrolyte Membranes
p.53
Influence of Infill Pattern and Infill Density on Mechanical Properties of 3D Printed Polylactic Acid (PLA)
p.61
Effects of Unidirectional Untreated Tiger Grass Fiber Reinforcement on Tensile Strength and Water Absorption of Epoxy Resin Composites
p.67
Mechanical Characterization of Silicone Rubber with Quail Eggshells as Bio-Based Filler
p.73
Effects of Post-Heat Treatments on Mechanical and Electrical Properties of 6201 Aluminum Alloy
p.81

Role of Ceramic Nanofillers in Enhancing Pore Formation and Conductivity of Solid Polymer Electrolyte Membranes

Article Preview

Abstract:

Solid polymer electrolyte (SPE) with PVdF polymer and LiBOB salt has been prepared with the doctor blade method. To improve the membrane ionic conductivity, TiO₂ was added in different variations: 0%, 5%, 10%, and 15%. Surface morphology analysis was performed using SEM and energy-dispersive X-ray (EDX) spectroscopy. The conductivity behavior was studied using AC impedance spectroscopy (EIS). SEM and EDXS analyses revealed that TiO₂ addition played a role in pore formation in the solid polymer electrolyte membrane. The highest room-temperature ionic conductivity of the PVdF–LiBOB solid polymer electrolyte system in this study was 4.65 mS cm⁻¹ at 10% TiO₂. It was also found that the agglomeration of TiO₂ particles on the surface of the membrane resulted in a decrease in ionic conductivity.

You might also be interested in these eBooks
The 9th Int. Conference on Materials Engineering and Applications (ICMEA) & the 14th Int. Conference on Nano and Materials Science (ICNMS) View Preview

Info:

Periodical:

Advances in Science and Technology (Volume 175)

Pages:

53-58

DOI:

https://doi.org/10.4028/p-xiAlX3

Citation:

Cite this paper

Online since:

May 2026

Authors:

Christin Rina Ratri*, Qolby Sabrina, Titik Lestariningsih, Adam Febriyanto Nugraha, Mochamad Chalid

Keywords:

Ceramic Filler, Dielectric Study, Li-Ion Battery, Polymer Electrolyte, TiO2

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

References

[1] Maia BA, Magalhães N, Cunha E, Braga MH, Santos RM, Correia N. Designing Versatile Polymers for Lithium-Ion Battery Applications: A Review. Polymers (Basel) [Internet]. 2022;14(3).

DOI: 10.3390/polym14030403

Google Scholar

[2] Bhute M V., Kondawar SB. Electrospun poly(vinylidene fluoride)/cellulose acetate/AgTiO2 nanofibers polymer electrolyte membrane for lithium ion battery. Solid State Ionics [Internet]. 2019;333:38–44.

DOI: 10.1016/j.ssi.2019.01.019

Google Scholar

[3] Rina Ratri C, Sabrina Q, Lestariningsih T, Zakiyyah S. Performance Enhancement of Poly (Vinyl Alcohol) Composite Polymer Electrolyte for Li-Ion Battery Through Salt Immersion Process. J Phys Sci [Internet]. 2022;33(3):33–44.

DOI: 10.21315/jps2022.33.3.3

Google Scholar

[4] El-zaher NA, Melegy MS, Guirguis OW. Thermal and Structural Analyses of PMMA/TiO2 Nanoparticles Composites. 2014;(July):859–70.

DOI: 10.4236/ns.2014.611083

Google Scholar

[5] Tsai CY, Liu YL. Building up ion-conduction pathways in solid polymer electrolytes through surface and pore functionalization of PVDF porous membranes with ionic conductors. J Memb Sci [Internet]. 2022;651(March).

DOI: 10.1016/j.memsci.2022.120456

Google Scholar

[6] Lin D, Liu W, Liu Y, Lee HR, Hsu PC, Liu K, et al. High Ionic Conductivity of Composite Solid Polymer Electrolyte via in Situ Synthesis of Monodispersed SiO2 Nanospheres in Poly(ethylene oxide). Nano Lett [Internet]. 2016;16(1):459–65.

DOI: 10.1021/acs.nanolett.5b04117

Google Scholar

[7] Hirankumar G, Mehta N. Effect of incorporation of different plasticizers on structural and ion transport properties of PVA-LiClO4 based electrolytes. Heliyon [Internet]. 2018;4(August):e00992.

DOI: 10.1016/j.heliyon.2018.e00992

Google Scholar

[8] Irzhak VI. Percolation Threshold in Polymer Nanocomposites. Colloid J [Internet]. 2021;83(1):64–9.

DOI: 10.1134/S1061933X21010063

Google Scholar

[9] Ghule B, Laad M. Polymer composites with improved dielectric properties: A review. Ukr J Phys [Internet]. 2021;66(2):166–77.

DOI: 10.15407/ujpe66.2.166

Google Scholar