Eggshell-Derived Magnetic CaAl Layered Double Hydroxides: Synthesis and Application as Methyl Orange Adsorbent

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In this study, CaAl-LDHs and magnetic-CaAl-LDHs were prepared through a straightforward co-precipitation method utilizing calcined eggshell as a sustainable calcium source. Physicochemical characterization via XRD, SEM, and FTIR revealed the microstructural properties of the synthesized materials. Results indicated that the Ca2+/Al3+ molar ratio was critical for optimizing methyl orange adsorption. The magnetite-incorporated variant demonstrated enhanced separability, while kinetic studies confirmed pseudo-second-order adsorption behavior for both adsorbents.

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23-29

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July 2026

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© 2026 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. El Gamal, F.M. Mohamed, M.A. Mekewi, F.S. Hashem, M.R. El-Aassar, R.E. Khalifa, Desalination and Water Treatment, 193 (2020), pp.142-151.

DOI: 10.5004/dwt.2020.25690

Google Scholar

[2] Y. Jiang, E. Sun, F. Zhao, Molecules, 29 (2024), p.3535.

Google Scholar

[3] Y.-H. Jiang, A.-Y. Li, H. Deng, C.-H. Ye, Y. Li, Environmental Science and Pollution Research, 26 (2019), pp.18343-18353.

DOI: 10.1007/s11356-019-05183-1

Google Scholar

[4] S. Suvokhiaw, C. Deeleepojananan, K. Konraeng, K. Laohhasurayotin, C. Suwa.nchawalit, Results in Surfaces and Interfaces, 20 (2025), p.100606.

DOI: 10.1016/j.rsurfi.2025.100606

Google Scholar

[5] S. Li, F. Wang, X. Jing, J. Wang, J. Saba, Q. Liu, L. Ge, D. Song, M. Zhang, Materials Chemistry and Physics, 132 (2012), pp.39-43.

DOI: 10.1016/j.matchemphys.2011.10.049

Google Scholar

[6] S. Suvokhiaw, A. Imyim, N. Sukpirom, Separation Science and Technology, 51 (2016), pp.2948-2957.

DOI: 10.1080/01496395.2016.1231206

Google Scholar

[7] T.-H. Kim, J.-A. Lee, S.-J. Choi, J.-M. Oh, International journal of molecular sciences, 15 (2014), pp.22563-22579.

DOI: 10.3390/ijms151222563

Google Scholar

[8] J. Wang, X. Guo, Journal of Hazardous Materials, 390 (2020), p.122156.

DOI: 10.1016/j.jhazmat.2020.122156

Google Scholar

[9] Y.S. Ho, G. McKay, Process Biochemistry, 34 (1999), pp.451-465.

DOI: 10.1016/S0032-9592(98)00112-5

Google Scholar

[10] I. Langmuir, Journal of the American Chemical Society, 40 (1918), pp.1361-1403.

DOI: 10.1021/ja02242a004

Google Scholar

[11] E.D. Revellame, D.L. Fortela, W. Sharp, R. Hernandez, M.E. Zappi, Cleaner Engineering and Technology, 1 (2020), p.100032.

DOI: 10.1016/j.clet.2020.100032

Google Scholar

[12] K.L. Tan, B.H. Hameed, Journal of the Taiwan Institute of Chemical Engineers, 74 (2017), pp.25-48.

DOI: 10.1016/j.jtice.2017.01.024

Google Scholar