New Electroconducting Radical Cation Salts Based on BEDT-TTF with 8,8’-Dibromo Cobalt Bis(Dicarbollide) Anion

Olga Kazheva; Grigorii Alexandrov; Andrey  Kravchenko; Vladimir Starodub; Irina  Lobanova; Igor Sivaev; Vladimir Bregadze; Lev Titov; Oleg Dyachenko

doi:10.4028/www.scientific.net/AST.54.331

Paper Titles

Low Temperature Growth of ZnO Nanorods by Chemical Bath Method
p.305

Inorganic Mesoporous Membrane for Potentially Used in Proton Exchange Membrane
p.311

Characteristics of the TiO₂/SnO₂ Thick Film Semiconductor Gas Sensor to Determine Fish Freshness
p.317

A New Synthesis Route to Prepare Polyaniline (PANI) Nanotubes Containing Magnetic Nanoparticles
p.325

New Electroconducting Radical Cation Salts Based on BEDT-TTF with 8,8’-Dibromo Cobalt Bis(Dicarbollide) Anion
p.331

Modulation of the Metallic Oxide Properties through of Soft Chemistry Techniques for Several Applications
p.337

CNT Based Sensors
p.343

Design and Fabrication of a MEMS AC Electric Current Sensor
p.350

A Review of Test Structures for Characterising Microelectronic and MEMS Technology
p.356

HomeAdvances in Science and TechnologyAdvances in Science and Technology Vol. 54New Electroconducting Radical Cation Salts Based...

New Electroconducting Radical Cation Salts Based on BEDT-TTF with 8,8’-Dibromo Cobalt Bis(Dicarbollide) Anion

Abstract:

New molecular conductors on the base of 8,8’-dibromo cobalt bis(dicarbollide) anion, (BEDT-TTF)2[8,8’-Br2-3,3’-Co(1,2-C2B9H10)2] (1), and (BEDT-TTF)[8,8’-Br2-3,3’-Co(1,2-C2B9H10)2] (2) were synthesized and their crystal structures and electrical conductivities were determined. Both radical cation salts prepared were found to be semiconductors. The introduction of two bromine atoms in the cobalt bis(dicarbollide) anion produces a strong effect on crystal structure and electrical conductivity of the prepared materials.