Fine Controlled Metallodendrimers for Advanced Nano-Catalysts

Kimihisa Yamamoto

doi:10.4028/www.scientific.net/AST.72.261

Paper Titles

Fabrication of an Intermediate-Temperature Anode-Supported Planar SOFC Via Tape Casting and Lamination
p.237

Improving the Oxidation Resistance of Fe-Cr-Mn Interconnector of Solid Oxide Electrolyte Fuel Cell with the Addition of Trace Elements
p.243

High Temperature - FTIR Characterization of Gadolinia Doped Ceria
p.249

A Novel Anode Based on Ni-Modified Perovskite for Direct Alcohol Solid Oxide Fuel Cells
p.255

Fine Controlled Metallodendrimers for Advanced Nano-Catalysts
p.261

Hybrid Membranes for Proton Exchange Fuel Cell
p.265

Investigation of a Passive DMFC Mini-Stack at Room Temperature
p.271

Pt Alloys on Carbon Nanostructures as Electrocatalysts for Direct Methanol Fuel Cell
p.277

Status and Challenges of Molten Carbonate Fuel Cells
p.283

HomeAdvances in Science and TechnologyAdvances in Science and Technology Vol. 72Fine Controlled Metallodendrimers for Advanced...

Fine Controlled Metallodendrimers for Advanced Nano-Catalysts

Abstract:

Dendrimers are highly branched organic macromolecules with successive layers or “generations” of branch units surrounding a central core. We show that tinchlorides complexes to the imines groups of a spherical polyphenylazomethine dendrimer in a stepwise fashion according to an electron gradient, with complexation in a more peripheral generation proceeding only after complexation in generations closer to the core has been completed. By further extending this strategy, it should be possible to control the number and location of metalchlorides incorporated into dendrimers for advanced nano-materials, such as nano-catalysts.

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Advances in Science and Technology (Volume 72)

Pages:

261-264

DOI:

https://doi.org/10.4028/www.scientific.net/AST.72.261

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Online since:

October 2010

Authors:

Kimihisa Yamamoto

Keywords:

Dendrimer, Metal Cluster, Metal-Assembling, Nanocatalyst

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