Modeling of Fractional Diffusion on a Catalytic Particle under Different Flow Conditions

Article Preview

Abstract:

Coupling diffusion and convection of species is relevant for optimization of diverse engineering processes, especially when chemical reactions are involved. In particular, the problem of predicting the flow of species into a particle is of large importance in the design of catalytic particles. A numerical framework using the Least Squares Spectral Element Method is implemented in order to analyze the species transport from a flow into a particle by a fractional constitutive law. The aim of this work is to investigate the qualitative change in the concentration profiles in the transition from Fickian to fractional anomalous transport inside the particle. A sample case is provided corresponding to a flow between two parallel plates and around a cylinder, coupled with species transport into the cylinder.

You might also be interested in these eBooks

Info:

Periodical:

Defect and Diffusion Forum (Volumes 323-325)

Pages:

121-126

Citation:

Online since:

April 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M. Küntz, P. Lavallée, Anomalous diffusion is the rule in concentration dependent diffusion processes, Journal of Physics D: Applied Physics 37(2004) L5.

DOI: 10.1088/0022-3727/37/1/l02

Google Scholar

[2] J. Klafter, I. Sokolov, Anomalous diffusion spreads its wings, PhysicsWorld Vol. 18 (2005) 29–32.

DOI: 10.1088/2058-7058/18/8/33

Google Scholar

[3] R. Klages, G. Radons, I. Sokolov, Anomalous Transport: Foundations and Applications, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim (2008).

DOI: 10.1007/s10955-009-9713-5

Google Scholar

[4] I. Podlubny, A. Chechkin, T. Skovranek, Y. Chen, B. M. V. Jara, Matrix approach to discrete fractional calculus II: Partial fractional differential equations, Journal of Computational Physics Vol. 228 (2009) 3137 – 3153.

DOI: 10.1016/j.jcp.2009.01.014

Google Scholar

[5] K. B. Oldham, Fractional differential equations in electrochemistry, Advances in Engineering Software 41 (2010) 9 – 12. Civil-Comp Special Issue.

Google Scholar

[6] A.M.A. El-Sayed, S.H. Behiry, W.E. Raslan, A numerical algorithm for the solution of an intermediate fractional advection dispersion equation, Communications in Nonlinear Science and Numerical Simulation, Volume 15, Issue 5, May 2010, Pages 1253-1258.

DOI: 10.1016/j.cnsns.2009.05.072

Google Scholar

[7] Y. Luchko, A. Punzi, Modeling anomalous heat transport in geothermal reservoirs via fractional diffusion equations, GEM - International Journal on Geomathematics - (2011) 1–20.

DOI: 10.1007/s13137-010-0012-8

Google Scholar

[8] G. Fix, J. Roop, Least squares finite-element solution of a fractional order two-point boundary value problem, Computers & Mathematics with Applications Vol. 48 (2004) 1017 – 1033.

DOI: 10.1016/j.camwa.2004.10.003

Google Scholar

[9] H. A. Jakobsen. 2008. Chemical Reactor Modeling,. Springer Berlin Heidelberg (2008).

Google Scholar

[10] M. M. J. Proot and M. I. Gerrtisma. 2002. Least-squares spectral elements applied to the Stokes problem. J. Comput. Phys. Vol. 181, 2 (September 2002), 454-477.

DOI: 10.1006/jcph.2002.7137

Google Scholar

[11] P.G. Clem, M. Rodriguez, J.A. Voigt and C.S. Ashley, U.S. Patent 6, 231, 666. (2001).

Google Scholar