Energy Transfer of a New Self-Activating Ba3TaGa3Si2O14: ySm3+, xNb5+ Phosphor Obtained by a Small Substitution of Nb5+ for Ta5+

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Self-activated multicolor phosphors are being used in more and more emerging fields. In order to explore the energy transfer between [NbO6]7- coordination groups and Sm3+ ions, a series of Ba3-ySmyTa1-xNbxGa3Si2O14 samples co-doped with Nb5+ and Sm3+ were prepared in this work, and the changes of luminous intensity under the condition of fixed Nb5+ concentration regulating Sm3+ concentration and fixed Sm3+ concentration regulating Nb5+ concentration were obtained respectively. By further fitting the emission decay curves of Sm3+ under two conditions, the decreasing average lifetime is obtained. Thermal stability tests of the samples also hinted the presence of such energy transfer. This regular change can provide a good reference for developing new self-activated phosphors.

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13-19

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October 2024

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© 2024 Trans Tech Publications Ltd. All Rights Reserved

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