For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Preface
Synthesis and Luminescent Properties of TiO2 Materials Single and Triple Doped with Rare Earth Ions (Sm3+ , Tb 3+ and Eu 3+)
p.3
Energy Transfer of a New Self-Activating Ba3TaGa3Si2O14: ySm3+, xNb5+ Phosphor Obtained by a Small Substitution of Nb5+ for Ta5+
p.13
Luminescence Properties of Cs3Cu2I5 Phosphors Powder with Solid State Method
p.21
Nonlinear Excitation of Color Centers in a LiF Crystal by Femtosecond Laser Radiation
p.27
Flame Front Model with the Clusters Condensation
p.39
Thermodynamic Calculations of the Main Characteristics of the Combustion Process of Pyrotechnic Nitrate-Metallized Mixtures with Additives of Organic and Inorganic Substances under External Thermal Influences
p.49
Assessment of the Influence of Features of Crack Formation in Reinforced Concrete Products on their Fire Resistance
p.61
Justification of the Efficiency of Application of Plaster for Fire Protection of Concrete Structures
p.69

Nonlinear Excitation of Color Centers in a LiF Crystal by Femtosecond Laser Radiation

Article Preview

Abstract:

Experiments were carried out in which the luminescence of color centers in lithium fluoride crystals was excited by two different femtosecond lasers with significantly different energies, durations and pulse repetition rates. It was established that in all experiments the main center, the luminescence of which was excited nonlinearly, was the F3+ color center. Unusual experimental data were obtained; a laser with low pulse energy (4 nJ) excited triplet luminescence of these centers (570 nm) but did not excite singlet luminescence (540 nm). Another laser with a higher pulse energy (0.3 mJ), on the other hand, excited singlet luminescence and did not excite triplet luminescence. A proposed diagram of energy levels and quantum transitions is presented, explaining the possible mechanisms of nonlinear excitation of luminescence in these experiments.

You might also be interested in these eBooks
11th International Conference on Materials Science (ICMS 2024) View Preview
Luminophores and Resistant Materials View Preview

Info:

Periodical:

Defect and Diffusion Forum (Volume 437)

Pages:

27-36

DOI:

https://doi.org/10.4028/p-4LpWfp

Citation:

Cite this paper

Online since:

October 2024

Authors:

Evgeni Fedorovich Martynovich*, Anastasia Sergeevna Frolova, Darmaa Unurbileg, Baterdene Ulziibayar, Odsuren Bukhtsooj, Jav Davaasambuu

Keywords:

Color Centers, Femtosecond, Kinetics, Lithium Fluoride, Luminescence, Nonlinearity, Quantum Transitions, Spectra

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

References

[1] T. Kurobori, T. Yamakage, Y. Hirose, K. Kawamura, M. Hirano, H. Hosono, Applications of wide-band-gap materials for optoelectronic functional devices fabricated by a pair of interfering femtosecond laser pulses, Jpn. J. Appl. Phys. 44 (2005) 910–913, doi.org/

DOI: 10.1143/JJAP.44.910

Google Scholar

[2] L.C. Courrol, R.E. Samad, L. Gomes, I.M. Ranieri, S.L. Baldochi, A. Zanardi de Freitas, N.D. Vieira Junior, Color center production by femtosecond pulse laser irradiation in LiF crystals, Opt. Express 12 (2) (2004) 288–293, doi.org/

DOI: 10.1364/OPEX.12.000288

Google Scholar

[3] E.F. Martynovich. Color centers in laser crystals (Tsentry okraski v lazernykh kristallakh), Irkutsk: Irkutsk State University Press, 2004, 226 pp. (in Russian).

Google Scholar

[4] A.P. Voitovich, V.S. Kalinov, V.V. Mashko, A.N. Novikov, L.P. Runets, A.P. Stupak, Transformation and formation of radiation-induced point defects in irradiated lithium fluoride crystals after their mechanical fragmentation, J. Appl. Spectrosc. 86 (1) (2019) 61–66, doi.org/

DOI: 10.1007/s10812-019-00781-w

Google Scholar

[5] Krivosheev N.D, Zilov S.A., Dresvyanskiy V.P., Martynovich E.F., Simulation of the dynamics of single F3+ color centers in LiF crystals, Journal of Luminescence, 257(8), (2023), 119688 doi.org/

DOI: 10.1016/j.jlumin.2023.119688

Google Scholar

[6] E.F. Martynovich, S.A. Zilov, V.P. Dresvyanskiy, Microspectroscopy of single color centers in alkaline halide crystals, Optics and Spectroscopy, 2023, Vol. 131, No. 5 P. 625-632 DOI: 10.61011/EOS.2023.05.56515.73-22, full-eos05.dvi (ioffe.ru)

DOI: 10.1134/s0030400x23020066

Google Scholar

[7] E.F. Martynovich, A.V. Kuznetsov, A.V. Kirpichnikov, E.V. Pestryakov, S. N. Bagayev, Formation of luminescent emitters by intense laser radiation in transparent media, Quantum Electron. 43 (5) (2013) 463–466

DOI: 10.1070/QE2013v043n05ABEH015117

Google Scholar

[8] Si Gao, Yan-Zhao Duan, Zhen-Nan Tian, Yong-Lai Zhang, Qi-Dai Chen, Bing-Rong Gao, Hong- Bo Sun, Laser-induced color centers in crystals, Optics & Laser Technology 146 (2022) 107527, doi.org/

DOI: 10.1016/j.optlastec.2021.107527

Google Scholar

[9] C.J. Stephen, B.L. Green, Y.N.D. Lekhai, L. Weng, P. Hill, S. Johnson, A.C. Frangeskou, P.L. Diggle, Y.C. Chen, M.J. Strain, E. Gu, M.E. Newton, J. M. Smith, P.S. Salter, G.W. Morley, Deep Three-Dimensional Solid-State Qubit Arrays with Long-Lived Spin Coherence, Phys. Rev. Appl. 12 (6) (2019) 064005, doi.org/

DOI: 10.1103/physrevapplied.12.064005

Google Scholar

[10] Xuedong Gao, Cui Yu, Shaochun Zhang, Haobin Lin, Jianchao Guo, Mengyu Ma, Zhihong Feng, Fang-Wen Sun, High sensitivity of diamond nitrogen-vacancy magnetometer with magnetic flux concentrators via enhanced fluorescence collection, Diamond and Related Materials Vol. 139,2023,110348, doi.org/

DOI: 10.1016/j.diamond.2023.110348

Google Scholar

[11] Philipp Reuschel, Mario Agio, and Assegid M. Flatae, Vector Magnetometry Based on Polarimetric Optically Detected Magnetic Resonance / Advanced. Quantum Technologies, 2022, 5, 2200077, doi.org/

DOI: 10.1002/qute.202200077

Google Scholar

[12] E.F. Martynovich, V.P. Dresvyansky, A.L. Rakevich, N.L. Lazareva, M. A. Arsentieva, A.A. Tyutrin, O. Bukhtsoozh, S. Enkhbat, P.V. Kostryukov, B. E. Perminov, A.V. Konyashchenko, Creating of luminescent defects in crystalline media by a scanning laser beam, Appl. Phys. Lett. 114 (12) (2019) 121901. doi.org/

DOI: 10.1063/1.5087688

Google Scholar

[13] Martynovich E.F., Chernova E.O., Dresvyansky V.P., et. al. Laser recording of color voxels in lithium fluoride, Optics & Laser Technology, 131, 106430, (2020). doi.org/

DOI: 10.1016/j.optlastec.2020.106430

Google Scholar

[14] Martynovich E.F., Nonlinear Photographic Material. Patent RU on Invention № 2781512 C1, 12.10.2022. patenton.ru/patent/RU2781512C1.pdf

Google Scholar

[15] Martynovich E.F., Nonlinear Photographic Luminescent Material. Patent RU on Invention № 2758567 C1, 29.10.2021. https://patenton.ru/patent/RU2758567C1.pdf

Google Scholar

[16] Martynovich E.F., Lazareva N.L., Zilov S.A. Creation of luminescent defects in crystals by coherent pairs of femtosecond laser pulses, Journal of Luminescence, 234, 117989. (2021). doi.org/

DOI: 10.1016/j.jlumin.2021.117989

Google Scholar

[17] S. A. Shlenova, V. O. Kompanets, V. P. Kandidov, S. V. Chekalin, and E. V. Vasil'ev. Channels of Filaments of Axially Asymmetric Optical Vortices at a Wavelength of 1800 nm in a LiF Crystal, JETP Letters, 2023, Vol. 117, No. 5, p.332–338

DOI: 10.1134/S0021364023600155

Google Scholar

[18] Radzhabov E. A. Luminescence centers in LiF:Li2O. Physica Status Solidi (B), V.115(1), K25–K28 (1983) doi.org/

DOI: 10.1002/pssb.2221150145

Google Scholar

[19] N. Shiran, A. Belsky, A. Gektin, S. Gridin, I. Boiaryntseva. Radioluminescence of color centers in LiF crystals. Radiation Measurements V. 56, 2013, pp.23-26 doi.org/10.1016/j.radmeas. 2013.01.047

DOI: 10.1016/j.radmeas.2013.01.047

Google Scholar

[20] T.T. Basiev, I.V. Ermakov, K.K. Pukhov. Singlet-singlet, singlet-triplet, and triplet-triplet transitions for F3+ color centers in LiF crystals / Proc. SPIE 3176, Tunable Solid State Lasers (1997) doi.org/

DOI: 10.1117/12.293442

Google Scholar

[21] V.V. Ter-Mikirtychev, T. Tsuboi, Two-Photon Excitation to the High-Lying Triplet State of F3+ Color Centers in LiF Crystals. Phys. Stat. Sol. B 190 (2), (1995) pp.347-351 doi.org/.

DOI: 10.1002/pssb.2221900203

Google Scholar

[22] G. Baldacchini, R.M. Montereali, and T. Tsuboi. Energy transfer among color centers in LiF crystals. Eur. Phys. J. D 17, 261–264 (2001) doi.org/

DOI: 10.1007/s100530170030

Google Scholar

[23] V. V. Ter-Mikirtychev, Spectroscopic Characteristics of Color Centers in LiF: F2+-OH-,Mg2+ Laser Crystals. J. Phys. Chem. Solids Vol 58. No. 6 (1997), pp.893-898 doi.org/10.1016/S0022- 3697(96)00227-2

DOI: 10.1016/s0022-3697(96)00227-2

Google Scholar

[24] Martynovich E.F., Balyunov D.V., Kuznetsov A.V., Kirpichnikov A.V., Trunov V.I., Pestryakov E.V., Bagayev S.N. Okrashivaniye shirokoshchelevykh kristallov intensivnym lazernym izlucheniyem (Coloring wide-gap crystals with intense laser radiation), Izvestiya vuzov. Fizika. – 2009. – T.52, №12-3,pp.191-197. https://www.elibrary.ru/down load/elibrary_24340123_61016061.pdf

Google Scholar

[25] Yang Zhang, Quanzhong Zhao, Huaihai Pan, Chengwei Wang, Jing Qian, and Zhanshan Wang, Simultaneous upconversion luminescence and color centers generated by femtosecond laser irradiation of LiF crystals, Chin. Opt. Lett. 14 (8), 083201 (2016). https://opg.optica.org/ col/abstract.cfm?URI=col-14-8-083201

DOI: 10.3788/col201614.083201

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.