Paper Titles

Characterization of Cuprous Oxide Thin Films for Application in Solar Cells
p.65

Optimization of Holographic Labels for Security Applications
p.74

Microstructure and Texture Control in Cold Rolled High Strength Steels
p.84

Investigation of Interdiffusion in High Entropy Alloys: Application of the Random Alloy Model
p.94

The Effect of Incomplete Solution Treatment on the Tensile Behavior and Mechanical Anisotropy of 2195 Aluminum Lithium Alloy
p.109

Effect of Heat Treatment on Microstructure and Mechanical Properties of 15-5 pH Stainless Steel for Fastener Applications
p.118

Ion Transport in Glass-Forming Calcium Potassium Nitrate: From Complex Behaviours to Unexpected Simplicities
p.140

Segregation and Phase Transitions in Grain Boundaries
p.160

The Vacancy-Wind Factor and the Manning Factor Occurring in Interdiffusion and Ionic Conductivity in Solids
p.170

HomeDiffusion FoundationsDiffusion Foundations Vol. 22The Vacancy-Wind Factor and the Manning Factor...

The Vacancy-Wind Factor and the Manning Factor Occurring in Interdiffusion and Ionic Conductivity in Solids

Article Preview

Abstract:

In crystalline solids, during such processes as chemical interdiffusion in alloys, ionic conductivity and the annealing out of radiation damage there will inevitably be a net flux of vacancies. In most cases, when different species of atoms have different jump rates with vacancies within a net flux of vacancies, the phenomenon of the vacancy-wind effect will occur. This effect was first discovered in the 1960s by the late Dr John Manning. It is a subtle phenomenon that comes about because of the local redistribution of the equilibrium concentration of vacancies with respect to two or more species of drifting atoms in a driving force. The effect is captured in various ‘vacancy-wind factors’ (some of which are now sometimes called Manning factors) which formally arise from non-zero off-diagonal Onsager phenomenological transport coefficients and non-unity values of the tracer correlation factors. In this paper, the effect is reviewed and discussed.

You might also be interested in these eBooks

Contemporary Advances in Diffusion in Solids

Info:

Periodical:

Diffusion Foundations (Volume 22)

Pages:

170-183

DOI:

https://doi.org/10.4028/www.scientific.net/DF.22.170

Citation:

Cite this paper

Online since:

May 2019

Authors:

Irina V. Belova, Graeme E. Murch*

Keywords:

Correlation Factors, Haven Ratio, Interdiffusion, Intrinsic Diffusion, Ionic Conductivity, Manning Factor, Vacancy-Wind Factor

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J.R. Manning, Diffusion Kinetics for Atoms in Crystals (Princeton, NJ: Van Nostrand) (1968).

[2] J.R. Manning, Phys. Rev. B, Vol. 4 (1971), p.1111.

[3] J.R. Manning, Can. J. Phys., Vol. 46 (1968), p.2633.

[4] J.R. Manning, Phys. Rev. Vol. 139 (1965), p.A2027.

[5] J.R. Manning, Acta Met., Vol. 15 (1967) p.817.

[6] R.E. Howard and J.R. Manning, Phys. Rev. Vol. 154 (1967) p.561.

[7] J.R. Manning, Met. and Mat. Trans. B, Vol. 1 (1970) p.499.

[8] J.R. Manning, Phys. Rev. Vol. 124 (1961) p.470.

[9] J.R. Manning, Diffusion Kinetics and Mechanisms in Single Crystals, Geochemical Transport and Kinetics, ed. A. W. Hofmann, B.J. Giletti, H.S. Yoder Jnr. and R.A. Yund, (Carnegie Inst. Washington Publications 634, pp.3-13 (1974).

[10] J.R. Manning, Phys. Rev. Vol 139 (1965) p. A126.

[11] J.R. Manning, Phys. Rev. Vol 125 (1962) p.103.

[12] G.E. Murch and R.J. Thorn, Phil. Mag. A, Vol. 39 (1979), p.259.

[13] A. R. Allnatt and A.B. Lidard, Atomic Transport in Solids (Cambridge University Press), (1993).

[14] G.E. Murch and I.V. Belova, Phil. Mag. A, Vol. 81 (2001), p.83.

[15] I.V. Belova, T. Ahmed, U. Sarder, A. V. Evteev, E.V. Levchenko, G.E. Murch, Phil. Mag. Vol.97 (2017) p.230.

[16] L.S. Darken, Trans. AIME, Vol. 180 (1948), p.430.

[17] L.K. Moleko, A.R. Allnatt and E.L. Allnatt, Phil. Mag. A, Vol. 59 (1989), p.141.

[18] I.V. Belova and G.E. Murch, Phil. Mag. A, Vol. 81 (2001), p.1749.

[19] A.R. Allnatt and E.L. Allnatt, Phil. Mag. A, Vol. 49, (1984), p.625.

[20] G.E. Murch, Phil. Mag. A, Vol. 46 (1982) p.575.

[21] I.V. Belova and G.E. Murch, Defect and Diffusion Forum, Vols. 273-276 (2008) p.431.

[22] A.B. Lidiard, Acta Met., Vol. 34 (1986) p.1487.

[23] K.L. Gosain, D.K. Chaturvedi. I.V. Belova and G.E. Murch, Defect and Diffusion Forum, Vols. 251-252 (2006) p.69.

DOI: 10.4028/www.scientific.net/ddf.251-252.69

[24] T.R. Paul, I.V. Belova, E.V. Levchenko, A.V. Evteev and G.E. Murch, Diffusion Foundations, Vol. 4 (2015), p.25.

[25] I.V. Belova and G.E. Murch, Phil. Mag. A., Vol. 81 (2001) p.1749.

[26] I.V. Belova and G.E. Murch, Phil. Mag. A., Vol. 80 (2000) p.1469.

[27] G.E. Murch and Z. Qin, Defect and Diffusion Forum, Vols. 109-110 (1994), p.1.

[28] G.E. Murch and C. M. Bruff, Chapter 5 in Diffusion in Solid Metals and Alloys, edited by H. Mehrer, Landolt-Bornstein, Group III, Condensed Matter, Vol 26, 1990, Springer.

DOI: 10.1007/b37801

[29] I.V. Belova and G.E. Murch, Acta Mat., Vol. 55 (2007), p.627.

[30] G.E. Murch, Solid State Ionics, Vol. 7 (1982), p.177.

[31] H. Sato and R. Kikuchi, J. Chem. Phys., Vol. 55 (1971) p.677.

[32] M. Chemla, Ann. Phys., Paris, Vol. 13 (1956), p.959.

[33] A.W. Imre, S. Voss and H. Mehrer, J. Non-Cryst. Solids, Vol. 333 (2004), p.231.

[34] A. Suzuki, H. Sato and R. Kikuchi, Phys. Rev. B, Vol. 29 (1984), p.3550.

[35] I.V. Belova and G.E. Murch, Diffusion Foundations, Vol. 6 (2015), p.44.

[36] I.V. Belova, A.R. Allnatt and G.E. Murch, Phil. Mag. Vol. 87 (2007), p.4169.