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Preface
Marking the Centennial of the Discovery of Alpha Silver Iodide
p.1
Interdiffusion in Ionic Compounds
p.44
Diffusion and Ion Conduction in Cation-Conducting Oxide Glasses
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Bombardment Induced Ion Transport through Ion Conducting Glasses
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Network Former Mixing (NFM) Effects in Ion-Conducting Glasses - Structure/Property Correlations Studied by Modern Solid-State NMR Techniques
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Bombardment Induced Ion Transport through Ion Conducting Glasses

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Abstract:

The recently developed bombardment induced ion transport (BIIT) technique is reviewed. BIIT is based on shining an energy-selected alkali ion beam at the surface of a sample of interest. Attachment of these ions leads to the build-up of a surface potential and a surface particle density. This in turn generates the corresponding gradients which induce ion transport towards a single metal electrode connected to the backside of the sample where it is detected as a neutralization current. Two different versions of BIIT are presented, i.) the native ion BIIT and ii.) the foreign ion BIIT. The former is demonstrated to provide access to absolute ionic conductivities and activation energies, the latter leads to the generation of electrodiffusion profiles. Theoretical modelling of these concentration profiles by means of the Nernst-Planck-Poisson theory allows to deduce the concentration dependence of diffusion coefficients.

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Periodical:

Diffusion Foundations (Volume 6)

Pages:

107-143

DOI:

https://doi.org/10.4028/www.scientific.net/DF.6.107

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Online since:

February 2016

Authors:

Karl Michael Weitzel

Keywords:

Activation Energy, Concentration Dependence of Diffusion Coefficients, Concentration Profiles, Diffusion Coefficients, Diffusion Profiles, Electrodiffusion, Glasses, Ion Beams, Ionic Conduction, Macroscopic Transport Theory, Mixed Alkali Effect, Nernst-Planck-Poisson Equations, NPP Theory, Polymer Films, Specific Conductivity, Thermionic Emission, ToF-SIMS

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