The Zinc Ferrite Decorated Unexfoliated Graphitic Carbon Nitride for Effective Antibiotic Degradation under Visible Light

Article Preview

Abstract:

The antibiotic pollutant treatment in wastewater using conventional method remains a challenge. One of the most fluoroquinolone antibiotics family used by human and animal cure is ciprofloxacin (CIP). CIP has exhibited as a recalcitrant compound in nature with concentration from ng to mg. To overcome this issue, recent technologies have applied such as photocatalysis technology for water decontamination. Furthermore, photocatalyst materials that used in this research were zinc ferrite and graphitic carbon nitride. A simple hydrothermal-coprecipitation method has succeed to synthesis zinc ferrite. While, unexfoliated graphitic carbon nitride (ZFO@ue-CN) was synthesized by calcination at 550 °C for 4 h under air condition. A heterostructure approach combining zinc ferrite and unexfoliated graphitic carbon nitride (ZFO@ue-CN) has been investigated as a potential solution. In this study, a ZFO@ue-CN was constructed by calcination method under atmosphere condition at 400 °C for 2 h. The ZFO@ue-CN has been characterized involving structural, morphological, and optical. Furthermore, ZFO@ue-CN exhibited excellent degradation performance with over 88% removal of ciprofloxacin. The heterojunction formation of ZFO@ue-CN nanocomposite provide more efficient electron transfer compared to single material. Combination between metal oxide@ue-CN can open up the new platform for simple material preparation, nevertheless it can keep the photodegradation performance. This result also emphasizes that the ZFO@ue-CN nanocomposites has prominent application for wastewater treatment.

You might also be interested in these eBooks

Info:

Pages:

37-43

Citation:

Online since:

January 2025

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2025 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Qarajehdaghi, M., et al., Quaternary composite of CdS/g-C3N4/rGO/CMC as a susceptible visible-light photocatalyst for effective abatement of ciprofloxacin: Optimization and modeling of the process by RSM and ANN. Process Safety and Environmental Protection, 2023. 169: pp.352-362.

DOI: 10.1016/j.psep.2022.11.030

Google Scholar

[2] Tamyiz, M., et al., Enhanced visible-light-responsive photodegradation of ciprofloxacin by direct Z-scheme ZnFe2O4@g-C3N4 nanocomposites. Journal of Photochemistry and Photobiology A: Chemistry, 2023. 443: p.114897.

DOI: 10.1016/j.jphotochem.2023.114897

Google Scholar

[3] Deng, Y., et al., Construction of plasmonic Ag modified phosphorous-doped ultrathin g-C3N4 nanosheets/BiVO4 photocatalyst with enhanced visible-near-infrared response ability for ciprofloxacin degradation. Journal of hazardous materials, 2018. 344: pp.758-769.

DOI: 10.1016/j.jhazmat.2017.11.027

Google Scholar

[4] Sha, J., et al., Diametrically opposite effect of Cu2+ on sulfamerazine and ciprofloxacin adsorption-photodegradation in g-C3N4/visible light system: behavior and mechanism study. Chemical Engineering Journal, 2022. 428: p.131065.

DOI: 10.1016/j.cej.2021.131065

Google Scholar

[5] Rafieenia, R., et al., Integration of microbial electrochemical systems and photocatalysis for sustainable treatment of organic recalcitrant wastewaters: Main mechanisms, recent advances, and present prospects. Science of The Total Environment, 2022: p.153923.

DOI: 10.1016/j.scitotenv.2022.153923

Google Scholar

[6] Tamyiz, M. and R.-A. Doong, Synergetic effect of adsorption and photocatalysis by zinc ferrite-anchored graphitic carbon nitride nanosheet for the removal of ciprofloxacin under visible light irradiation. Open Chemistry, 2023. 21(1).

DOI: 10.1515/chem-2022-0304

Google Scholar

[7] Lan, Z.-A., G. Zhang, and X. Wang, A facile synthesis of Br-modified g-C3N4 semiconductors for photoredox water splitting. Applied Catalysis B: Environmental, 2016. 192: pp.116-125.

DOI: 10.1016/j.apcatb.2016.03.062

Google Scholar

[8] Mafa, P.J., et al., Multi-elemental doped g-C3N4 with enhanced visible light photocatalytic Activity: Insight into naproxen degradation, kinetics, effect of electrolytes, and mechanism. Separation and Purification Technology, 2022. 282: p.120089.

DOI: 10.1016/j.seppur.2021.120089

Google Scholar

[9] Deng, X., et al., Boosting interfacial charge separation and photocatalytic activity of 2D/2D g-C3N4/ZnIn2S4 S-scheme heterojunction under visible light irradiation. Journal of Alloys and Compounds, 2022. 894: p.162209.

DOI: 10.1016/j.jallcom.2021.162209

Google Scholar

[10] Zhang, Y., et al., CNTs boosting superior cycling stability of ZnFe2O4/C nanoparticles as high-capacity anode materials of Li-ion batteries. Journal of Alloys and Compounds, 2022: p.165135.

DOI: 10.1016/j.jallcom.2022.165135

Google Scholar

[11] Yang, H., et al., An efficient construction method of S-scheme Ag2CrO4/ZnFe2O4 nanofibers heterojunction toward enhanced photocatalytic and antibacterial activity. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022. 641: p.128603.

DOI: 10.1016/j.colsurfa.2022.128603

Google Scholar

[12] Wang, S. and J. Wang, Magnetic 2D/2D oxygen doped g-C3N4/biochar composite to activate peroxymonosulfate for degradation of emerging organic pollutants. Journal of Hazardous Materials, 2022. 423: p.127207.

DOI: 10.1016/j.jhazmat.2021.127207

Google Scholar

[13] Wu, Y., et al., Boosting 2e− oxygen reduction reaction in garland carbon nitride with carbon defects for high-efficient photocatalysis-self-Fenton degradation of 2, 4-dichlorophenol. Applied Catalysis B: Environmental, 2022. 307: p.121185.

DOI: 10.1016/j.apcatb.2022.121185

Google Scholar

[14] Nguyen, T.B., C. Huang, and R.-A. Doong, Photocatalytic degradation of bisphenol A over a ZnFe2O4/TiO2 nanocomposite under visible light. Science of the Total Environment, 2019. 646: pp.745-756.

DOI: 10.1016/j.scitotenv.2018.07.352

Google Scholar

[15] Fan, G., et al., Magnetically separable ZnFe2O4/Ag3PO4/g-C3N4 photocatalyst for inactivation of Microcystis aeruginosa: Characterization, performance and mechanism. Journal of Hazardous Materials, 2022. 421: p.126703.

DOI: 10.1016/j.jhazmat.2021.126703

Google Scholar

[16] AL-Shwaiman, H.A., et al., Fabrication of intimately coupled CeO2/ZnFe2O4 nano-heterojunction for visible-light photocatalysis and bactericidal application. Materials Chemistry and Physics, 2022: p.125759.

DOI: 10.1016/j.matchemphys.2022.125759

Google Scholar

[17] Matli, P.R., et al., Fabrication, characterization, and magnetic behavior of porous ZnFe2O4 hollow microspheres. International Nano Letters, 2015. 5(1): pp.53-59.

DOI: 10.1007/s40089-014-0135-2

Google Scholar

[18] Nguyen, T.B. and R.-A. Doong, Heterostructured ZnFe2O4/TiO2 nanocomposites with a highly recyclable visible-light-response for bisphenol A degradation. RSC Advances, 2017. 7(79): pp.50006-50016.

DOI: 10.1039/c7ra08271a

Google Scholar

[19] Sarkar, P., S. De, and S. Neogi, Microwave assisted facile fabrication of dual Z-scheme g-C3N4/ZnFe2O4/Bi2S3 photocatalyst for peroxymonosulphate mediated degradation of 2, 4, 6-Trichlorophenol: the mechanistic insights. Applied Catalysis B: Environmental, 2022. 307: p.121165.

DOI: 10.1016/j.apcatb.2022.121165

Google Scholar

[20] Shi, Y., et al., Engineering of 2D/3D architectures type II heterojunction with high-crystalline g-C3N4 nanosheets on yolk-shell ZnFe2O4 for enhanced photocatalytic tetracycline degradation. Materials Research Bulletin, 2022: p.111789.

DOI: 10.1016/j.materresbull.2022.111789

Google Scholar