Tribological Behavior of Al₂O₃-ZrO₂ + 3Y₂O₃ Composites

Article Preview

Abstract:

This study investigates the tribological behavior of composites based on Al2O3–ZrO2 stabilized with 3 mol. % Y2O3 (ZTA – zirconia-toughened alumina), prepared using spark plasma sintering (SPS) technology. The composites were characterized in terms of microstructure, mechanical properties, and wear resistance in a dry ball-on-flat configuration. SEM analysis confirmed a homogeneous and fine-grained microstructure without porosity, with Al2O3 grain sizes of 200–400 nm and ZrO₂ grain sizes of 100–200 nm. Measurements revealed high Vickers hardness (1566.7 ± 133.6 MPa), fracture toughness (6.4 ± 0.29 MPa·m¹ᐟ²), nanoindentation hardness (25.94 ± 2.35 GPa), and Young’s modulus (365.9 ± 18.2 GPa). The coefficient of friction ranged from 0.40 to 0.53 depending on the load, and the specific wear rate was extremely low (4.81 × 10⁻⁷ to 5.08 × 10⁻⁷ mm³/Nm). Analysis of the wear track revealed predominantly abrasive wear without significant fragmentation or delamination. The results demonstrate that optimized microstructure, proper phase stabilization, and a high degree of densification enable the preparation of composites with an excellent combination of hardness, toughness, and tribological resistance. These materials are suitable for demanding applications in industry, energy, and biomedicine.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

77-82

Citation:

Online since:

March 2026

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Chevalier, L. Gremillard, Ceramics for Medical Applications: A Picture for the next 20 years. Journal of the European Ceramic Society, 29, 7 (2009), https://doi.org/10.1016/j.jeurceramsoc. 2008.08.025.

DOI: 10.1016/j.jeurceramsoc.2008.08.025

Google Scholar

[2] M.H. Ghaemi, S. Reichert, A. Krupa, M. Sawczak, A. Zykova, K. Lobach, S. Sayenko, Y. Svitlychnyi, Zirconia ceramics with additions of Alumina for advanced tribological and biomedical applications, Ceramic International 43, 13 (2017) 9746-9752, https://doi.org/10.1016/j.ceramint. 2017.04.150.

DOI: 10.1016/j.ceramint.2017.04.150

Google Scholar

[3] Lawn, B.R., Principles of Fracture Toughness Measured by Indentation and Calibration Approaches, Journal of Materials Science, 33, 20 (1998) 4947-4956.

Google Scholar

[4] R.H.J. Hannink, P.M. Kelly, B.C. Muddle, Transformation Toughening in Zirconia-Containing Ceramics, Journal of the American Ceramic Society, 83, 3 (2000) 461-487. https:// doi.org/.

DOI: 10.1111/j.1151-2916.2000.tb01221.x

Google Scholar

[5] Y.J. He, A.J.A. Winnubst, A.J Burggraaf, H. Verweij, P.G.T. Van der Varst, G de With, Sliding Wear of ZrO2-Al2O3 Composite Ceramics, Journal of the European Ceramic Society (1997) 1371-1380.

DOI: 10.1016/s0955-2219(96)00239-7

Google Scholar

[6] W.C. Oliver, G.M. Pharr, An Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments, Journal of Materials Research, 7, 6 (1992) 1564-1583.

DOI: 10.1557/JMR.1992.1564

Google Scholar

[7] O.O. Vasylkiv, Y. Sakka, V.V. Skorokhod, Hardness and fracture toughness of alumina-doped tetragonal zirconia with different yttria contents, Journal of the European Ceramic Society, 23, 10 (2003) 1669-1676.

DOI: 10.2320/matertrans.44.2235

Google Scholar

[8] J. Chevalier, L. Gremillard, S. Deville, Low-temperature degradation of zirconia and implications for biomedical implants, Biomaterials, 30, 8 (2007) 1558-1566, https:// doi.org/.

DOI: 10.1146/annurev.matsci.37.052506.084250

Google Scholar

[9] Y.M. Chen, B. Rigaut, F. Armanet, Wear Behaviour of Partially Stabilized Zirconia at High Sliding Speed, Journal of the European Ceramic Society, 6 (1990) 383-390.

DOI: 10.1016/0955-2219(90)90006-2

Google Scholar

[10] Basu, B., Vleugels, J., Van Der Biest, O., Microstructure–toughness–wear relationship of tetragonal zirconia ceramics, Journal of the European Ceramic Society, 24, 7 (2004) 2031-2040.

DOI: 10.1016/S0955-2219(03)00355-8

Google Scholar