PCD tools, especially curve edge PCD compound tools are used widely in machining nonferrous and non-metal materials with high efficiency and precision because of their excellent cutting properties. But high quality grinding of PCD tools is the uppermost obstacle in application because there are great difficulties to profile and sharpen edge in grinding, especially for milling cutter and drill with curve edge. This paper studied technology of wire EDG curve edge PCD compound tools by wire electrical discharge grinding machine with five-axis CNC system. The grinding quality was evaluated by scanning electron microscope (SEM) and roughometer. Three steps processing technique (roughing, finishing and fine finishing) and optimal process parameters of wire EDG PCD tools were recommended after considering synthetically the surface quality, precision and machining efficiency. The results met the requirement of high surface quality, precision and efficiency. This paper also applied successfully the optimal technology to grind a PCD milling cutter with outer and inner blade by electrical discharge grinding machine with five-axis CNC system. By the optimal parameters, the process yielded high precision of ±4.3µm and low roughness of 0.30µm. Experiment results have great practical significance to the high precise and efficient wire EDG of PCD tools.