Influence of Excess Bi2O3 and Na2Co3 on Crystal Structure and Microstructure of Bismuth Sodium Titanate Ceramics

Abstract:

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This study investigated the influence of excess Bi2O3 and Na2CO3 on the crystal structure, microstructure and dielectric properties of (Bi0.5Na0.5)TiO3 (BNT) ceramics. The BNT ceramics were synthesized using the solid-state reaction method with various excess Bi2O3 and Na2CO3 levels (0, 1, 2, 3 and 4 mol%). The X-ray characterization revealed that all samples had a rhombohedral structure. A pure perovskite phase was obtained in all samples. The lattice parameter a tended to increase with increased excess Bi2O3 and Na2CO3 content in the calcined powders and sintered ceramics. The average particle size increased while, the average grain size tended to decreased with increased of excess Bi2O3 and Na2CO3 content. The depolarization temperature (Td) and the Curie temperature (Tc) were slightly decreased with the increase of excess Bi2O3 and Na2CO3 content. The dielectric properties were related to the density.

Info:

Periodical:

Key Engineering Materials (Volumes 474-476)

Edited by:

Garry Zhu

Pages:

1711-1714

DOI:

10.4028/www.scientific.net/KEM.474-476.1711

Citation:

P. Sittiketkron et al., "Influence of Excess Bi2O3 and Na2Co3 on Crystal Structure and Microstructure of Bismuth Sodium Titanate Ceramics", Key Engineering Materials, Vols. 474-476, pp. 1711-1714, 2011

Online since:

April 2011

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$35.00

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