Research on the Asphaltene Structure and Thermal Analysis in Catalytic Aquathermolysis of Heavy Oil

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Abstract:

As an irreversible viscosity reduction way, catalytic aquathermolysis of heavy oil is given close attention by scholars at home and abroad, and a high content of asphaltene in heavy oil is the major cause for the high viscosity of heavy oil. Through the use of IR spectrum and TG-DTA, this paper analyzes the asphaltene structure and thermal analysis before and after the catalytic aquathermolysis reaction, and the result shows some changes in the heavy component structure in the asphaltene after the reaction, a reduction in some unsaturated structures, an increase in saturated structures, a reduction in long-chain structures, an increase in short-chain structures, and an increase in light components. Thermal analysis shows that part of the asphaltenes can be converted into alkane soluble substance. The catalyst acts on the heteroatoms in asphaltenes, which partly changes the asphaltene structure and makes it cracked to some extent, so as to lead to the lower viscosity of heavy oil.

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Key Engineering Materials (Volumes 474-476)

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893-897

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April 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] Hu Jianyi, Niu Jiayu.China's heavy oil and asphaltic sand resources [J]. World Petroleum Industry, 1998, 5(9): 13-19.

Google Scholar

[2] Liu Wenzhang , The development model of thermal recovery of heavy oil reservoirs [M]. Beijing: Petroleum Industry Press(1998).

Google Scholar

[3] Hyne J B. Synopsis Report No. 50, Aquathermolysis[R]. AOSTRA Contracts No. 11103103B/C, (1986).

Google Scholar

[4] Clark P D, Hyne J B. Studies on the chemical reactions of heavy oils under steam stimulation condition [J]. AOSTRA J Res, 1990, 29(6): 29-39.

Google Scholar

[5] Hyne J B, Tyrer J D. Use of hydrogen-free carbon monoxide with steam in recovery of heavy oil at low temperatures [P]. US 4487264, (1984).

DOI: 10.1016/0360-3199(85)90190-9

Google Scholar

[6] Jiang Sheng-jian, Liu Xi-lin, Liu Yong-jian, et al. In situ upgrading heavy oil by aquathermolytic treatment under steam injection conditions[C]. SPE 91973, 2005: 1-4.

DOI: 10.2118/91973-ms

Google Scholar

[7] Wang Zijun. The chemistry and physics of petroleum asphaltenes Part Ⅲ (The study methods of chemical structure of asphaltenes [J]. Petroleum Asphalt, 1995 , 9(4): 32-38.

Google Scholar

[8] Wang Yuanqing, Chen Yanling, Xia Fei, et al. Study on thermal cracking for Liaohe heavy oil during steam soak[J]. Geological Science and Technology Information, 2007, 26(2): 81-85.

Google Scholar

[9] Zhang Guicai, Pan Binlin, Ge Jijiang, et al. Study on thermal cracking for Liaohe heavy oil during steam soak [J]. Oilfield Chemistry, 2007, 24(1): 19-23.

Google Scholar