Solvothermal Synthesis and Characterization of Two Iron Complexes

Abstract:

Two iron complexes, Fe₃(dtdb)₂(HCO₂)₂(DMF)₂(H₂O)₂ (1) and Fe(bpy)(Hdtdb)(H₂O) (2) were solvothermally synthesized and characterized by single crystal X-ray diffraction. Fe₃(dtdb)₂(HCO₂)₂(DMF)₂(H₂O)₂ (1) shows 2D layer structure crystallized in a triclinic with space group P-1 and cell parameters, a = 8.5591(10) nm, b = 11.2502(13) nm, c = 11.4370(14) nm, α = 90.687(2)º, β = 110.275(2)º , γ = 90.712(2)º, and Z = 1. Fe(bpy)(Hdtdb)(H₂O) (2) shows surper- molecular architecture crystallized in a triclinic with space group P-1 and cell parameters, a = 8.286(12) nm, b = 11.5937(16) nm, c = 11.8477(17) nm, α = 93.932(3)º, β = 102.442(3)º, γ = 97.117(3)º, and Z = 1.

• Periodical: Key Engineering Materials (Volume 492)
• Pages: 324-327
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.492.324
• Online since: September 2011
• Authors: Ya Wei Hu, Yang Min Ma
• Keywords: Crystal Structure, Iron Complex, Solvothermal Synthesis

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