Studies of Hydroxyapatite Thin Coating Produced by Dual RF Magnetron Sputtering for Biomedical Applications

Article Preview

Abstract:

In this present work, we characterize HAp thin films deposited by dual magnetron sputtering device DMS on silicon (Si/HAp). The sputtering RF power was varied from 90 watts to 120 watts and deposition times from 60 to 180 minutes. The argon and oxygen pressure were fixed at 5.0 mTorr and 1.0 mTorr, respectively. Grazing incidence X-ray diffraction (GIXRD) from synchrotron radiation, infrared spectroscopy (FTIR) and atomic force microscopy (AFM) were used for the structural characterization. At lower deposition times, a crystalline phase with preferential orientation along apatite (002) and a disordered nanocrystalline phase were identified. The coating crystallinity was improved with the increase of the deposition time besides the sputtering power.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 493-494)

Pages:

473-476

Citation:

Online since:

October 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] V. Nelea, C. Morosanu, M. Iliescu, I.N. Mihailescu, Microstruture and mechanical properties of hydroxyapatite thin films grown by RF magnetron sputtering, Surface and Coatings Techonology, 173, 315-322 (2003).

DOI: 10.1016/s0257-8972(03)00729-1

Google Scholar

[2] Xuebin Zheng, Minhui Huang, Chuanxian Ding, Bond strength of plasma-sprayed hydroxyapatite/Ti composite coatings, Biomaterials, 21, 841-849 (2000).

DOI: 10.1016/s0142-9612(99)00255-0

Google Scholar

[3] Yunzhi Yang, Kyo-Han Kim, Joo L. Ong, A review on calcium phosphate coatings produced using a sputtering process – an alternative to plasma spraying, Biomaterials, 26, 327-337 (2005).

DOI: 10.1016/j.biomaterials.2004.02.029

Google Scholar

[4] J.Z. Shi, C.Z. Chen, H.J. Yu and S.J. Zhang, Application of magnetrons sputtering for producing bioactive ceramic coatings on implant materials, Bull. Mater. Sci., Vol 31, 6, 877-884 (2008).

DOI: 10.1007/s12034-008-0140-z

Google Scholar

[5] A.R. Boyd, H. Duffy, R. McCann, M.L. Cairns, B.J. Meenan, The influence of argon gas pressure on co-sputtered calcium phosphate thin films, Nuclear Instruments and Methods in Physics Research, B 258 421-428 (2007).

DOI: 10.1016/j.nimb.2007.02.072

Google Scholar

[6] E. van der Wal, J.G.C. Wolke, J.A. Jansen, A.M. Vredenberg, Initial reactivity of rf magnetron sputtered calcium phosphate thin films in simulated body fluids, Applied Surface Science, 246 183-192 (2005).

DOI: 10.1016/j.apsusc.2004.11.006

Google Scholar

[7] Mello A, Hong Z, Rossi AM, et al. Osteoblast proliferation on hydroxyapatite thin coatings produced by right angle magnetron sputtering, Biomedical Materials Vol 2 Issue: 2 67-77 (2007).

Google Scholar

[8] Hong Z, Mello A, Yoshida T, Luan L, Stern PH, Rossi A, Ellis DE, Ketterson JB. Osteoblast proliferation on hydroxyapatite coated substrates prepared by right angle magnetron sputtering. J Biomed Mater Res A. 93(3) 878-85 (2010).

DOI: 10.1002/jbm.a.32556

Google Scholar