Structure and Growth Kinetics Features of Ceramic Coatings Produced on Ti-6Al-4V Alloy by Plasma Arc Oxidation

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Abstract:

Ceramic coatings were fabricated by plasma arc oxidation on Ti6Al4V alloy in phosphate –containing solution. The growth rate, microstructure and phase composition of ceramic coatings were investigated using coating thickness gauge, scanning electron microscope (SEM) and X-Ray diffraction (XRD). After plasma arc oxidation treatment, the microstructure of the remained Ti6Al4V alloy substrate remains unchanged and no hardening zone in the substrate is found. Ceramic coating formed on Ti6Al4V alloy surface by alternating-current plasma arc oxidation contains two layers: an outer layer and an inner layer. The outer layer coating consists of a large amount of rutile and a little anatase. But in the inner layer, anatase becomes a main phase while the rutile fraction obviously decreases, which indicates that phase transformation of anatase into rutile occurs in the duration of oxidizing process. In the mean time, with increasing treatment duration, coating growth varies from rapidness to tardiness accompanied by gradually roughening in appearance.

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Key Engineering Materials (Volumes 512-515)

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1036-1039

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y.M. Wang, B.L. Jiang, T.Q Lei, Dependence of growth features of plasma arc oxidation coatings of titanium alloy on control modes of alternate pulse. Materials Letters, J. 58 (2004) 1907~1911.

DOI: 10.1016/j.matlet.2003.11.026

Google Scholar

[2] H.H.Wu, X.Y.Lu, B.H. Long, The effects of cathodic and anodic voltages on the characteristics of porous nanocrystalline titania coatings fabricated by plasma arc oxidation. Materials Letters, J. 59 (2005) 370~375.

DOI: 10.1016/j.matlet.2004.10.019

Google Scholar

[3] Y.M. Wang, D.C. Jia, L.X. Guo, T.Q. Lei, Effect of discharge pulsating on plasma arc oxidation coatings formed on Ti-6Al-4V alloy. Materials Chemistry and Physics, J. 90 (2005) 128~133.

DOI: 10.1016/j.matchemphys.2004.10.025

Google Scholar

[4] C.Leyens and M.Peters, Titanium and Titanium Alloys,Chemical Industry Press, Beijing,2006.

Google Scholar