Corrosion Behavior of Al2O3 Ceramics in the Acid and Alkaline Solutions

Article Preview

Abstract:

Al2O3 materials were used in a very wide range due to its good mechanical properties and relative low manufacture cost. The corrosion resistance of Al2O3 materials in acid, alkaline and sea water solutions gained more and more attention because many application situations are severe and the working life is shorten due to the corrosion. In this paper, the corrosion behavior of Al2O3 based materials in acid and alkaline solutions was studied and effect of corrosion time on the corrosion behavior of Al2O3 materials was investigated. The microstructure of as prepared Al2O3 materials was characterized by SEM. Possible corrosion process and mechanism was discussed in details. The results reveal that the as prepared Al2O3 materials show better corrosion resistance in alkaline solution than in acid solutions. In both acid and alkaline conditions, the corrosion mainly occurs in the grain boundary. Mass loss increased with increasing corrosion time, while the corrosion rate was decreased.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 512-515)

Pages:

509-512

Citation:

Online since:

June 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] W. H. Tuan & W. B. Chou, The corrosion behaviour of Al2O3 toughened by Ag particles. J. Euro.Ceram. Soc. 16, (1996) 583-586.

Google Scholar

[2] A. Gergely,É. Pfeifer,. I Bertóti., T.Török, & E.Kálmán, Corrosion protection of cold-rolled steel by zinc-rich epoxy paint coatings loaded with nano-size alumina supported polypyrrole. Corrosion Science 53, (2011) 3486-3499.

DOI: 10.1016/j.corsci.2011.06.014

Google Scholar

[3] M. G Lawson, F. S. Pettit & J. R. Blachere, Hot corrosion of alumina. J. Mater. Res. 8, , (1993).1964-1971

DOI: 10.1557/jmr.1993.1964

Google Scholar

[4] K.Oda, & T. Yoshio, Hydrothermal corrosion of alumina ceramics. J. Am. Ceram. Soc. 80, (1997)3233-3236.

DOI: 10.1111/j.1151-2916.1997.tb03258.x

Google Scholar

[5] T.Hirata, T.Morimoto, S. Ohta & N.Uchida, Improvement of the corrosion resistance of alumina chromia ceramic materials in molten slag. J. Euro. Ceram. Soc. 23, (2003) 2089-2096.

DOI: 10.1016/s0955-2219(03)00023-2

Google Scholar

[6] H.Sarpoolaky, S.Zhang, & W. E. Lee Corrosion of high alumina and near stoichiometric spinels in iron-containing silicate slags. J. Euro.Ceram. Soc. 23, (2003)293-300,.

DOI: 10.1016/s0955-2219(02)00170-x

Google Scholar

[7] K.Natesan, Corrosion performance of alumina scales in coal gasification environments. Mater. at High Temp. 14, (1997)137-145.

DOI: 10.1080/09603409.1997.11689538

Google Scholar

[8] G. Gunnarsson, B. Johannesson, Corrosion of Sodium beta '- Alumina Membranes in Molten Sodium Hydroxide. J. Am. Ceram. Soc. 94, (2011)988-990.

DOI: 10.1111/j.1551-2916.2011.04418.x

Google Scholar

[9] T.Sato, S. Sato, A.Okuwaki & S. Tanaka, Corrosion behavior of alumina ceramics in caustic alkaline-solutions at high temperatures. J. Am. Ceram. Soc. 74, (1991)3081-3084.

DOI: 10.1111/j.1151-2916.1991.tb04304.x

Google Scholar

[10] L.Ćurković, M. F.Jelača & S. Kurajica, Corrosion behavior of alumina ceramics in aqueous HCl and H2SO4 solutions. Corrosion Science 50, (2008)872-878.

DOI: 10.1016/j.corsci.2007.10.008

Google Scholar