3D Interconnetive Porous Silica Ceramics Prepared by Gel Casting with Egg White Protein as a Foaming Agent

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Highly porous silica ceramics were produced by gel casting with egg white protein (EWP) as a foaming agent and evaluated by measuring the porosity, mechanical strength and microstructure. After drying, the green bodies were debindered and sintered at 1300°C for 4 h. The influences of the EWP content on the open porosity as well as the strength were investigated. The porosity of the obtained porous silica ceramics was within 70.2%-86.1%, the bending strength decreased from 6.81 MPa to 5.48 MPa. It was found that the strength dependence of the porosity was well described by a modified exponential relation of the form σ=σ0exp(-BP), where P is the porosity and B is a constant (B = 1.37 was obtained by fitting the experimental data). This finding is in agreement with other literature data and seems to indicate a common feature of all porous ceramics.

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Key Engineering Materials (Volumes 512-515)

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555-558

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] T.Y. Yang, Porous mullite composite with controlled pore structure processed using a freeze casting of TBA-based coal fly ash slurries, Resour. Conserv. Recy. (2010) doi:10.1016/ j.resconrec.2009. 12.012.

DOI: 10.1016/j.resconrec.2009.12.012

Google Scholar

[2] H. Schneider, J. Schreuer, B. Hildmann, Structure and properties of mullite-A review, J. Eur. Ceram. Soc. 28 (2008) 329–344.

Google Scholar

[3] G.H. Bai, W. Teng, X.G. Wang, et al, Processing and kinetics studies on the alumina enrichment of coal fly ash by fractionating silicon dioxide as nano particles, Fuel Process Technol. 91 (2010) 175–184.

DOI: 10.1016/j.fuproc.2009.09.010

Google Scholar

[4] H. Xu, J.C. Liu, A.R. Guo, H.Y. Du, Z.G. Hou, Porous silica ceramics with relatively high strength and novel bi-modal pore structure prepared by a TBA-based gel-casting method, Ceram. Int. (2011).

DOI: 10.1016/j.ceramint.2011.09.013

Google Scholar

[5] O. Lyckfeldt, J. Brandt, S. Lesca, Protein forming - a novel shaping technique for ceramics, J. Eur. Ceram. Soc. 20 (2000) 2551-2559.

DOI: 10.1016/s0955-2219(00)00136-9

Google Scholar

[6] I. Garrn, C. Reetz, N. Brandes, L.W. Kroh, H. Schubert, Clot-forming: the use of proteins as binders for producing ceramic foams. J. Eur. Ceram. Soc. 24 (2004) 579–587.

DOI: 10.1016/s0955-2219(03)00259-0

Google Scholar

[7] E. Allen Foegeding, P.J. Luck, J.P. Davis, Factors determining the physical properties of protein foams. Food Hydrocolloids 20 (2006) 284–292.

DOI: 10.1016/j.foodhyd.2005.03.014

Google Scholar

[8] R.W. Rice, Relation of tensile strength-porosity effects in ceramics to porosity dependence of Young's modulus and fracture energy, porosity character and grain size, Mater. Sci. Eng. A 112, (1989) 215-224.

DOI: 10.1016/0921-5093(89)90361-4

Google Scholar