In Situ Polymerization and Photophysical Properties of Poly(p-phenylene Benzobisoxazole)/Nano-Sized TiO2 Fibers

Hu Wang; Ji Ping Liu

doi:10.4028/www.scientific.net/KEM.531-532.605

Paper Titles

The Humidity Sensitive Behavior of Poly(Ethyleneimine)/Multiwall Carbon Nanotube Composite Films
p.588

A Preparation Method of Diamond Specimens Using an Advanced FIB Microscopy for Micro and Nanoanalysis
p.592

Microstructure and Mechanical Properties of a Nb-Microalloyed Medium Carbon Steel Treated by Quenching-Partitioning Process
p.596

The Specific Binding between Galactose Group and Ricinus Communis Agglutinin (RCA) Investigated with Microcantilever
p.600

In Situ Polymerization and Photophysical Properties of Poly(p-phenylene Benzobisoxazole)/Nano-Sized TiO₂ Fibers
p.605

Preparation of Poly(γ-Glutamic Acid)/Montmorillonite Superabsorbent Nanocomposite
p.609

Synthesis of Zinc Doped-Biphasic Calcium Phosphate Nanopowder via Sol-Gel Method
p.614

Microstructure and Melting Behavior of Rapid Solidified Au-Ag-Ge Alloy
p.618

Effect of Accumulative Roll Bonding Process with Inter-Cycle Heat Treatment on Microstructure and Microhardness of AA1050 Alloy
p.623

HomeKey Engineering MaterialsKey Engineering Materials Vols. 531-532In Situ Polymerization and Photophysical...

In Situ Polymerization and Photophysical Properties of Poly(p-phenylene Benzobisoxazole)/Nano-Sized TiO₂ Fibers

Abstract:

Poly (p-phenylene benzobisoxazole)/Nano-sized titanium dioxide (PBO/TiO₂) composites with different TiO₂ compositions were prepared through in situ polymerization and the fibers had been successfully spun via dry-jet wet spinning technique. PBO/TiO₂ composite fibers were characterized by FTIR spectroscopy, Ubbelohde capillary viscometer, TG analyses and so on. Mechanical property of the fibers was investigated before and after UV accelerated aging which being exposed under ultraviolet radiation for up to 100 hours. Results showed that the molecular weight of PBO in the Nano composites was less declined with low content of TiO₂; the thermal degradation temperature of PBO/TiO₂ fibers were at less 10°C higher than that of pure PBO fiber in the atmosphere of N₂; The pure PBO had a large deterioration in mechanical properties, and in the initial exposure time tensile strength of fibers dropped slowly after TiO₂ adding in. From these results, the nano-TiO₂ had good UV-aging shielding efficiency for PBO fiber.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Key Engineering Materials (Volumes 531-532)

Pages:

605-608

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.531-532.605

Citation:

Cite this paper

Online since:

December 2012

Authors:

Hu Wang, Ji Ping Liu

Keywords:

In Situ Polymerization, Nanocomposite, Nano-Titanium Dioxide (Nano-TiO₂）, Poly(p-phenylene benzobisoxazole) (PBO)

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] J.F. Wolfe: Rigid-rod Polymer Synthesis: Mat. Rec. Symp. Proc , Vol. 134 (1989), p.83.

Google Scholar

[2] Tadao. Kuroki: Journal of Applied Polymer Science, Vol. 65 (1997), No.5, p.1031.

Google Scholar

[3] H.J. Zhu and S.L. Yang: Polymers for Advanced Technologies, Vol. 20 (2009) No.3, p.351.

Google Scholar

[4] X.H. Xu and Z.W. Han: Journal of Applied Polymer Science, Vol. 116 (2010), No. 1, p.455.

Google Scholar

[5] Han. Gi. Chae: Journal of Applied Polymer Science, Vol. 100 (2006) No. 1, p.791.

Google Scholar

[6] C.H. Zhang: Journal of Applied Polymer Science, Vol. 120 (2011), No. 4, p.2468.

Google Scholar

[7] Yukihiro. Abe, Go. Matsuoka and Kohei. Kiriyama: U.S. Patent 7, 357, 982. (2008).

Google Scholar

[8] D.H. Xiao, E.J. Shawn and K. Satish: Macromol. Mater. Eng, Vol. 288 (2003), p.823.

Google Scholar

[9] C.J. Zhou and Q.L. Wu: Journal of Applied Polymer Science, Vol. 124 (2012) No.6, p.4740.

Google Scholar

[10] Chin. J, Forster. A and Rice. K: Polym Degrad Stabil, Vol.92 ( 2007), p.1234.

Google Scholar