Charge Storage Characteristics of Ni-NiOx Core-Shell Nanocrystals Embedded in SiO2 Gate Oxide

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Abstract:

The memory characteristics of Ni-NiOx core-shell nanocrystals (NCs) in the metal-oxide-semiconductor (MOS) capacitor structure were investigated. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) confirm the formation of the spherically shaped, well isolated, and uniformly distributed Ni NCs surrounded by NiOx (~1nm) in SiO2 gate oxide. The Ni-NiOx NCs embedded in SiO2 exhibited a large memory window of 9.8 V as well as efficient programming/erasing speed and improved retention characteristics of about 10 years. A possible band model needed for injection efficiency of carriers was given by considering the electron/hole barrier width and the additional interface states through the NiOx shell layer.

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Key Engineering Materials (Volumes 562-565)

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731-736

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July 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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