Effect of Er3+ Doped on Photocatalytic Properties of ZnO-TiO2 Nanofibers

Article Preview

Abstract:

Er3+ doped ZnO-TiO2 nanofibers with diameter of 100~200 nm were prepared by electrospinning mothed after calcined at high temperature, using polyvinylpyrrolidone(PVP), Zn(NO3)2·6H2O, Er(NO3)3·5H2O, Ti(OC4H9)4 as raw materials. The composite nanofibers were characterized by XRD, SEM, and UV-V respectively. Effects of different calcined temperatures on structure and photocatalytic degradation were investigated. The results indicated that the crystallinity becomes better with the increasing of calcination temperature. The composite nanofibers had the best effects of photocatalytic degradation of methylene blue, when Er3+ doping content was 0.3 wt.% and calcined temperature was 500 °C.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

258-262

Citation:

Online since:

November 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] WANG C, AO Y, WANG P, et al, Preparation, characterization and photocatalytic activity of a novel composite photocatalyst: ceria-coated activated carbon, J. J Hazard Mater. 184 (2010) 1-5.

DOI: 10.1016/j.jhazmat.2010.07.034

Google Scholar

[2] WIWAT N, SIA YASUNEE N, WIRAT J , SANTI M, SUPAPAN S, Structural characterization and morphology of electrospun TiO2 nanofibers, J. Materials Science and Engineering. 131 (2006) 147-155.

Google Scholar

[3] Pilizzettie E. Fine particles science and technology from micro to nanoparticles. London: Kluwer, Ltd, 1996, p.657~673.

Google Scholar

[4] Ishizumi A, Taguchi Y, Yamamoto A, et al, Abrication and optical properties of Eu3+-doped ZnO nanospheres and nanorods, J. Materials Science and Engineering. 146 (2008) 212-215.

DOI: 10.1016/j.mseb.2007.07.030

Google Scholar

[5] Kong X Y, Ding Y, Wang Z L, Metal-semiconductor Zn-ZnO core-shell nanobelts and nanotubes, J. Journal of Physical Chemistry B. 108 (2004) 570-574.

DOI: 10.1021/jp036993f

Google Scholar

[6] Li XZ, Li FB, Yang CL, et al, Photocatalytic activity of WOX-TiO2 under visible light irradiation, J. Photochem Photobiol A. 141 (2001) 209-217.

DOI: 10.1016/s1010-6030(01)00446-4

Google Scholar

[7] XU A W, GAO Y, LIU H Q, The Preparation, characterization and their Photocatalytic activites of rare-earth-doped TiO2 nanoparticles, J. J Catal. 207 (2002) 151-157.

DOI: 10.1006/jcat.2002.3539

Google Scholar

[8] Jing Liqiang, Sun Xiaojun, Cai Wimin, et al, Photoluminescence of Ce doped TiO2 nanoparticles and their Photocatalytic activity, J. Acta Chim sinica. 61 (2003) 1241-1245.

Google Scholar

[9] Ju-Young Park, Je-Jung Yun, Cheol-Ho Hwang, et al, Influence of silver doping on the phase transformation and crystallite growth of electrospun TiO2 nanofibers, J. Materials Letters. 64 (2010) 2692-2695.

DOI: 10.1016/j.matlet.2010.09.008

Google Scholar

[10] Deuk-Yong Lee, Bae-Yeon Kim, Nam-Ihn Cho, et al, Electrospun Er3+-TiO2 nanofibrous films as visible light induced photocatalysts, J. Current Applied Physics. 11 (2011) 324-327.

DOI: 10.1016/j.cap.2011.03.022

Google Scholar