Preparation and Optical Properties of Lanthanum Doped Ultra-Fine TiO2 Photocatalyst

Article Preview

Abstract:

In the experiment, the tetrabutyl titanate and lanthanum nitrate were used as raw material, lanthanum doped TiO2 powder was prepared by sol-gel method, were characterized by using XRD, UV-vis, IR to determine the crystal structure, grain size and spectral properties. The results showed that the calcination temperature is 600 °C, lanthanum doping ratio is 0.6%, the amount of catalyst is 50mg and the visible light photocatalytic degradation time at 60min, the degradation of methyl orange solution rate of 20mg/L can reach 36%. Samples with anatase as the main, in the catalyst preparation process, due to the synergistic effects of lanthanum doping, the modified TiO2 absorption band of different redshift, enhanced the catalytic activity of TiO2 visible light.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

267-271

Citation:

Online since:

November 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Kitano M, Matsuok M, Ueshima M, et al. Recent developments in titanium oxide-based photocatalysts. Appl. Catal. A, 2007, 325(1): 1 14.

Google Scholar

[2] Chen X B, Mao S S. Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem. Rev., 2007, 107(7): 2891 2959.

DOI: 10.1021/cr0500535

Google Scholar

[3] Fuerte A, Hernández-Alonso M D, Maira A J, et al. Visible light-activated nanosized doped-TiO2 photocatalysts. Chem. Com-mun., 2001, 2001(24): 2718 2719.

DOI: 10.1039/b107314a

Google Scholar

[4] Ohno T, Akiyoshi M, Umebayashi T, et al. Preparation of S-doped TiO2 photocatalysts and their photocatalytic activities under visible light. Appl. Catal. A, 2004, 265(1): 115 121.

DOI: 10.1016/j.apcata.2004.01.007

Google Scholar

[5] Livraghi S, Paganini M C, Giamello E, et al. Origin of photoactivity of nitrogen-doped titanium dioxide under visible light. J. Am. Chem. Soc., 2006, 128(49): 15666 15671.

DOI: 10.1021/ja064164c

Google Scholar

[6] JIN Zhi-Liang, LV Gong-Xuan. Modification of TiO2 photocatalysts with metalloid anions and the applicaton in salt solution system. Journal of Inorganic Materials, 2011, 26(6): 571 578.

DOI: 10.3724/sp.j.1077.2011.00571

Google Scholar

[7] Klosek S., Raftery D., Visible Light Driven V-Doped TiO2 Photocatalyst and its Photooxidation of Ethanol, J. Phys. Chem. B, 105, 2815-2819, (2001).

DOI: 10.1021/jp004295e

Google Scholar

[8] Bashir S., Zhang H., Guo J., Liu J., Green Chemistry Derived Metal-modified Titania used for Dye-sensitized Solar Cell, TechConnect World Conference and Expo, Santa Clara, California, June 18-21, (2012).

Google Scholar