In Situ Formation of Mullite-Al₂O₃ Refractory Ceramic from Al-Matrix Mixtures

Abstract:

Two types of mullite-Al₂O₃ composites were designed and sintered in situ from different composition containing Al composites e.g. kaolin, alumina hydroxide and calcined bauxite etc, and auxiliary additives. The phase composition and microstructure were studied using X-ray diffraction (XRD) and scanning electron microscope (SEM) techniques. Bulk density, apparent porosity, thermal expansion coefficient and bending strength were also measured. The two samples exhibited XRD reflections characteristic of alumina and mullite phases. The amount of these phases depended on starting batch compositions, and reaction of starting and auxiliary materials together to form mullite. Because of in-situ formation of mullite fiber, the bulk density and bending strength were improved and apparent porosity was decreased for the composites with uniform microstructure. The presence of high mullite phase was found to decrease the thermal expansion coefficient. The potential effect of these morphologies and phase on properties was discussed. These mullite-Al₂O₃ composite was expected to have major applications in the areas of refractory material.

• Periodical: Key Engineering Materials (Volumes 602-603)
• Pages: 628-631
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.602-603.628
• Online since: March 2014
• Authors: Xing Yong Gu, Ping Li, Wei Xia Dong, Ting Luo
• Keywords: Mullite-Al₂O₃, Thermal Expansion Coefficient

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