Low Temperature Sintering of (Ba0.98Ca0.02)(Sn0.04Ti0.96)O3 Ceramics Using CuO-B2O3 as a Sintering Additive

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The effects of CuO-B2O3 (CBO) additive on densification, microstructure, and electrical properties of (Ba0.98Ca0.02)(Sn0.04Ti0.96)O3 (BCST) cermaics were investigated. The phase compositions, microstructure, dielectric, ferroelectric and piezoelectric properties of BCST ceramics were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), precision impedance analyzer, ferroelectric tester and quasi-static piezoelectric constant testing meter, respectively. The results show that CuO-B2O3 (CBO) frit can improve the densification and promote low-temperature sintering of BCST ceramics prepared by a conventional solid-state reaction method. Dense BCST ceramics with CBO can be sintered at temperatures as low as 1175 °C, which is approximately 275 °C less than the sintering temperature of pure BCST. When sintered at 1200 °C, the optimized properties of the BCST ceramics with 0.5 wt% CBO were obtain as ε = 1206, d33 = 346 pC/N, kP = 0.39, tgδ = 0.009.

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Key Engineering Materials (Volumes 602-603)

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813-816

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March 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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